Tuning tear and slow crack growth resistance of linear low-density polyethylene resins through partial replacement of 1-butene with 1-hexene

Jandaghian, Mohammad Hossein; Sepahi, Abdolhannan; Hosseini, Shahin; Esmaeilzade, Romina; Nikzinat, Ehsan; Salimzadeh, Ali; Zaeri, Reza; Masoori, Maryam

doi:10.1080/10601325.2023.2251534

Journal of Macromolecular Science, Part A

2023

DOI: 10.1080/10601325.2023.2251534

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Tuning tear and slow crack growth resistance of linear low-density polyethylene resins through partial replacement of 1-butene with 1-hexene

Mohammad Hossein Jandaghian,

Abdolhannan Sepahi,

Shahin Hosseini

et al.

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2023

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Splitting for strength: Manipulating polymerization reactor split ratios to control mechanical and rheological properties in bimodal polyethylene resins

Jandaghian,

Sepahi,

Hosseini

et al. 2023

J of Applied Polymer Sci

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This study integrates advanced mathematical modeling and experimental methodologies to investigate the simultaneous impact of modifications in the split ratio and molecular weight (MW) of chains on the rheological and mechanical properties of bimodal polyethylene (BiPE) resins. The outcomes underscored the viability of fine‐tuning the molecular weight distribution (MWD) of a BiPE resin by augmenting the MW of high molecular weight (HMW) chains while simultaneously diminishing their proportion in the final alloy formulation. In addition, the experimental results illuminated the prospect of attaining a targeted melt flow index for the final polymers by elevating the MW of HMW chains alongside an increase in the proportion of low molecular weight chains. Significantly, these adjustments resulted in remarkable enhancements in the shear thinning index and strain hardening modulus of the fabricated resins.

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Splitting for strength: Manipulating polymerization reactor split ratios to control mechanical and rheological properties in bimodal polyethylene resins

Jandaghian,

Sepahi,

Hosseini

et al. 2023

J of Applied Polymer Sci

Self Cite

View full text Add to dashboard Cite

show abstract

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Tuning tear and slow crack growth resistance of linear low-density polyethylene resins through partial replacement of 1-butene with 1-hexene

Cited by 1 publication

References 27 publications

Splitting for strength: Manipulating polymerization reactor split ratios to control mechanical and rheological properties in bimodal polyethylene resins

Splitting for strength: Manipulating polymerization reactor split ratios to control mechanical and rheological properties in bimodal polyethylene resins

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