Tuning Structural Topologies of Three Photoluminescent Metal–Organic Frameworks via Isomeric Biphenyldicarboxylates

C 30 H54N 2 O7, orthorhombic, P21212 (no. 18), a = 11.6240(9) Å, b = 12.9628(11) Å, c = 10.5166(9) Å, V = 1584.6(2) Å 3 , Z = 2, CCDC no.: 1555754The crystal structure is shown in the figure. Table 1 and 2 contain details on crystal structure and measurement conditions as well as a list of atoms including atomic coordinates and displacement parameters. Source of materialsThe title compound was prepared by accident. Firstly, a synthesized aromatic acid, 2,2′-biphenyldicarboxylic acid (A.R.) and tetraethylammonium (25% aqueous solution, C. R.) were

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“…MOFs [3][4][5][6]. Here the crystal structure of the title structure is reported to enrich the related organic structures.…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C₃₀H₅₄N₂O₇

Cheng

Zai

2017

Zeitschrift Für Kristallographie - New Crystal Structures

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“…[1,1′-Biphenyl]-2,2′-dicarboxylic acid, which is an important medical intermediate, is widely used in MOF chemistry to explore di erent properties such as magnetism [1], uorescent probe [2] and so on [3,4]. In the aforementioned reaction triethylamine is monoprotonated by the dicarboxylic acid.…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C₂₀H₂₅NO₄

Hou

Zeng

2016

Zeitschrift Für Kristallographie - New Crystal Structures

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“…which exhibits a rare binodal 4,6-connected fsh net. To the best of our knowledge, only two CPs with this topology (one noninterpenetrating 21 and one interpenetrating fsh net 22 ) have been reported lately, and the structure of the complex presented here is the first cobalt(II) complex with fsh network. Furthermore, the complex as a heterogeneous catalyst for degrading congo red and the fluorescence property have been investigated.…”

mentioning

confidence: 86%

Assembly and Catalytic Properties of a 3D (4,6)-connected Cobalt-organic Framework with fsh Topology

Ming¹,

Zhang²,

Li³

et al. 2014

Bulletin of the Korean Chemical Society

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During the past two decades, the construction of novel functional coordination polymers (CPs) has become one of the most intense areas for the sake of inosculating the aesthetic features of intriguing crystalline materials with diverse structural topologies and potential applications in areas of magnetism, adsorption, separation, catalysis, luminescence, and so on.1-7 Choosing well-designed organic ligands containing modifiable backbones is the key step and the most effective and facile method to build novel CPs. Therefore, significant interest has arisen in the structural tuning of coordination polymers via rational selection of with N and/ or O-donors as coordination sites in the construction of crystalline materials with the three-dimensional (3D) CPs, such as pcu, msw, mok, dia, srs, cds, rtl, etc. [8][9][10][11][12][13][14][15][16][17][18] However, there is an unfavorable lack of research about the higherdimensional networks with the mixed nodes, such as (3,6)-, (4,6)-, (4,8)-, (4,10)-, and (4,12)-connected networks, which are considered to be much more difficult to obtain these networks. 19,20The bridging ligand 1,2,4,5-benzenetetracarboxylic acid (H 4 btec) has various coordination modes to the metal centers and links metal ions to construct metal-carboxylate frameworks which can be further elevated through the incorporation of bridging flexible two-connector N-containing ligands. Herein, we anticipate 1,1-(1,4-butanediyl)bis-1H-benzimidazole (bbbm) ligand, which possesses a favorable N-ligating donor for metal ions and a more flexible coordination fashion due to the existence of cis-or trans-configuration resulting from the free rotation of the benzimidazole rings. In continuation of our exploratory research toward developing a new example of 3D CPs with the mixed nodes based on btec 4 ligand, we have been successfully synthesized and structurally characterized a new 3D cobalt(II) coordination polymer [Co(btec) 0.5 (bbbm) 0.5 ] n . which exhibits a rare binodal 4,6-connected fsh net. To the best of our knowledge, only two CPs with this topology (one noninterpenetrating 21 and one interpenetrating fsh net 22

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Tuning Structural Topologies of Three Photoluminescent Metal–Organic Frameworks via Isomeric Biphenyldicarboxylates

Cited by 188 publications

References 48 publications

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C₃₀H₅₄N₂O₇

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C₃₀H₅₄N₂O₇

Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C₂₀H₂₅NO₄

Assembly and Catalytic Properties of a 3D (4,6)-connected Cobalt-organic Framework with fsh Topology

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Tuning Structural Topologies of Three Photoluminescent Metal–Organic Frameworks via Isomeric Biphenyldicarboxylates

Cited by 188 publications

References 48 publications

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C30H54N2O7

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C30H54N2O7

Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C20H25NO4

Assembly and Catalytic Properties of a 3D (4,6)-connected Cobalt-organic Framework with fsh Topology

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Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C₃₀H₅₄N₂O₇

Crystal structure of bis(tetraethylammonium) [1,1′-biphenyl]-2,2′-dicarboxylate trihydrate, C₃₀H₅₄N₂O₇

Crystal structure of triethylammonium 2′-carboxy-[1,1′-biphenyl]-2-carboxylate, C₂₀H₂₅NO₄