Tunable Optoelectronic Properties of Polydimethylsiloxane-Arylazopyrazole Flexible Composite

Uba, Ikemefuna; Ghebreyessus, Kesete; Geddis, Demetris; Hömmerich, U.

doi:10.1109/southeastcon45413.2021.9401853

Cited by 2 publications

(12 citation statements)

References 8 publications

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“…An irradiation with green light of the PDMS–AAP composite resulted in the original absorbance spectrum of the trans state being retrieved with almost 100% of the original intensity. This distinct behavior is due to the efficient reversible isomerization the AAP unit embedded in the PDMS matrix [ 21 , 22 ]. Comparison of the index of refraction in the trans and cis states as well as that of pure PDMS of the same thickness were described in our recently reported studies [ 21 ].…”

Section: Resultsmentioning

confidence: 99%

“…The arylazopyrazole (AAP) molecular switch was synthesized following procedures developed in our previous studies using commercially available aniline [ 21 , 22 ].…”

Section: Methodsmentioning

confidence: 99%

“…Polydimethylsiloxane–arylazopyrazole (PDMS–AAP) composite was fabricated by spin-coating PDMS elastomer-curer gel doped with 0.02M of AAP on glass substrate and curing at 150 °C for 22 min as described in our previous work [ 21 ].…”

Section: Methodsmentioning

confidence: 99%

“…If successfully integrated into a host that promises stoichiometric freedom, not only can a photoswitch induce a new set of indices in the material, but it can also reversibly switch the value through photoisomerization. Among several photoswitches, aryazopyrazole (AAP) was successfully embedded into polydimethylsiloxane (PDMS) [ 21 , 22 ]. The PDMS–AAP composite exhibited actuation, high index (≈2.0), and regulation of same via isomerization.…”

Section: Introductionmentioning

confidence: 99%

“…We note that AAPs have thermal stability and half-life of 1000 days, unlike ubiquitous azobenzene, and they attain high switching efficiency [ 23 ]. In particular, the AAP derivative reported in [ 21 , 22 ] achieved ≈ 100% efficiency in solid matrix over repeated switching. It is then logical to examine suitability of this composite for nanophotonic circuits.…”

Section: Introductionmentioning

confidence: 99%

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A Study of Wave Confinement and Optical Force in Polydimethlysiloxane–Arylazopyrazole Composite for Photonic Applications

et al. 2022

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A refractive index of dielectrics was modified by several methods and was known to have direct influence on optical forces in nanophotonic structures. The present contribution shows that isomerization of photoswitching molecules can be used to regulate refractive index of dielectrics in-situ. In particular, spectroscopic study of a polydimethylsiloxane–arylazopyrazole (PDMS–AAP) composite revealed that refractive index of the composite shifts from 2.0 to 1.65 in trans and cis states, respectively, of the embedded AAP. Based on this, a proposition is made for a waveguide structure, in which external UV/Vis source reversibly regulates the conformation of the PDMS–AAP core. Computational study is performed using Maxwell’s equations on buried waveguide structure. The simulation, implemented in PYTHON, sequentially utilizes empirical refractive indices of the composite in the isomeric states in lieu of regulation by a source. The simulation revealed highly confined wave propagations for injected signals of 340 and 450 nm wavelengths. It is observed that the cis state suppresses higher order mode when propagating UV wavelength but allows it for visible light. This modal tuning demonstrated that single mode can be selectively excited with appropriate waveguide dimensions. Further impact of the tuning is seen in the optical force between waveguide pair where the forces shift between attractive and repulsive in relation to the isomeric state of the PDMS–AAP core. These effects which stem from the adjustment of refractive index by photoisomerization suggests that in-situ regulation of index is achievable by successful integration of photoswitching molecules in host materials, and the current PDMS–AAP composites investigated in this study can potentially enhance nanophotonic and opto-mechanical platforms.

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Section: Resultsmentioning

confidence: 99%

“…The arylazopyrazole (AAP) molecular switch was synthesized following procedures developed in our previous studies using commercially available aniline [ 21 , 22 ].…”

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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A Study of Wave Confinement and Optical Force in Polydimethlysiloxane–Arylazopyrazole Composite for Photonic Applications

et al. 2022

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Numerical analysis of the propagation modes of photo-switching PDMS-arylazopyrazole optical waveguide and thin-film spectroscopic characterization

Mirbagheri

Uba

Ghebreyessus

et al. 2023

Integrated Optics: Devices, Materials, and Technologies XXVII

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A new light responsive arylazopyrazole (AAP) containing polymer matrix thin film is fabricated by spincoating of different concentrations of the AAP azo dye into the polydimethylsiloxane (PDMS) polymer at 150°C. The new AAP molecular switch was also used to fabricate a solid-state PDMS-AAP waveguide by contact lithography and soft replica modeling methods in the micrometer scale. The refractive index of the spin-coated photoswitchable material can be modulated via the reversible trans-to-cis photoisomerization behavior of the AAP unit using different concentrations. When 0.01 M solution of the AAP unit was used, the refractive of the composite was 2.32 in the trans state and dropped to 1.85 in the cis state in the operating wavelength of 340 nm. At higher concentrations of 0.020 and 0.03 M, a wide refractive index tuning is achieved under the same wavelength. In 0.030 M the refractive index was 2.65 for the trans state and 2.0 for the cis state. The results suggest that the increase in refractive index tuning is related to the concentration of the AAP unit of the composite film. Theoretically, the spectral properties of the composite film are also simulated with two methods: 1) the Maxwell Equations; and 2) the frequency dependent finite element, showing excellent agreement for the different propagation modes of the proposed waveguide for regulated signals of 365/525 nm wavelengths. Furthermore, the photoisomerization of the PDMS-AAP thin film is analyzed with UV-vis spectroscopy to demonstrate the isomerization responses of the AAP moiety in the solid state. Additionally, preliminary photomechanical actuation properties of the composite film have been investigated. The PDMS-AAP waveguide described in this study provides a new approach for optically tunable photonics applications in the Visible-IR region.

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Tunable Optoelectronic Properties of Polydimethylsiloxane-Arylazopyrazole Flexible Composite

Cited by 2 publications

References 8 publications

A Study of Wave Confinement and Optical Force in Polydimethlysiloxane–Arylazopyrazole Composite for Photonic Applications

A Study of Wave Confinement and Optical Force in Polydimethlysiloxane–Arylazopyrazole Composite for Photonic Applications

Numerical analysis of the propagation modes of photo-switching PDMS-arylazopyrazole optical waveguide and thin-film spectroscopic characterization

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