Tunable magnetism and electron correlation in titanium-based Kagome metals RETi3Bi4 (RE = Yb, Pr, and Nd) by rare-earth engineering

Abstract

Rare-earth engineering is an effective way to introduce and tune the magnetism in topological Kagome magnets, which has been acting as a fertile platform to investigate the quantum interactions between geometry, topology, spin, and correlation. Here we report the structure and properties of three newly discovered titanium-based Kagome metals RETi3Bi4 (RE = Yb, Pr, and Nd) with various magnetic states. They all crystalize in the orthogonal space group Fmmm (No. 69), where slightly distorted Ti Kagome lattice, RE triangular lattice, Bi honeycomb and triangular lattices stack along the a axis. By changing the rare earth atoms on RE zag-zig chains, the magnetism can be tuned from nonmagnetic YbTi3Bi4 to short-range ordered PrTi3Bi4 (Tanomaly ~ 8.2 K), and finally to ferromagnetic NdTi3Bi4 (Tc ~ 8.5 K). The resistivity and specific heat capacity measurements demonstrate an evolution of electron correlation and density of states near the Fermi level with different rare earth atoms. In-situ resistance measurements of NdTi3Bi4 under high pressure further reveal a potential relationship between the electron correlation and ferromagnetic ordering temperature. These results highlight RETi3Bi4 as a new family of topological Kagome magnets to explore nontrivial band topology and exotic phases in Kagome materials.

Evolution of Highly Anisotropic Magnetism in the Titanium-Based Kagome Metals LnTi3Bi4 (Ln: La···Gd3+, Eu2+, Yb2+)

“…The authors declare no competing financial interest. Alongside this manuscript, several related works were posted on arXiv within a short time period, 58,59 though authors do not address the rotational dependence of the in-plane/out-of-plane magnetization. One work has rotation dependence but examines only the Sm compound.…”