Abstract:Using a new semi-rigid tetradentate ligand and two cyanometalate building blocks with different steric hindrance, a Fe2Co triangular unit [(Tp)FeIII(CN)3]2CoII(bpmb)·2H2O [1; Tp = hydrotris(pyrazolyl)borate; bpmb = 1,2-bis(3-(2-pyridyl)pyrazol-1-ylmethyl)benzenes] and a Fe2Co2 square unit {[(pzTp)FeIII(CN)3]2[CoII(bpmb)]2}·[(pzTp)FeIII(CN)3]2·4H2O [2; pzTp = tetrakis(pyrazolyl)borate] were synthesized via tunable assembly. Both compounds adopt cis arrangement because of the structural distorted semi-rigid bpmb… Show more
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