“…However, the Tropical Atlantic Ocean is the second largest source of CO2 from the ocean to the atmosphere, mainly due to equatorial upwelling and warm waters (Landschützer et al, 2014, Takahashi et al, 2009. The ocean dynamics of the surface current system (e.g., Johns et al, 1998;Salisbury, et al, 2011;Johns et al, 2021) and the large freshwater input from the Amazon River (Liang et al, 2020), coupled with precipitation dynamics (Ibánhez et al, 2015;Utida et al, 2019), also add a biogeochemical complexity to the western Tropical Atlantic Ocean (da Cunha & Buitenhuis, 2013). Such complexity is reflected in the pronounced spatial and temporal variability of the marine carbonate system and particularly in the sea-air CO2 exchanges (Körtzinger, 2003;Cooley et al, 2007;Lefèvre et al, 2010;Valerio et al, 2021;Louchard et al, 2021;Mu et al, 2021).…”