The visible light‐induced photolysis of trityl salts with different anions was investigated in vacuo. The following order of photostability, determined from the rates of decoloration of the dichloroethane solutions of these salts, was found: (C6H5)3C+PF6− > (C6H5)3C+AsF6− > (C6H5)3C+BF4− > (C6H5)3C+SbCl6− ≥ (C6H5)3C+FeCl4−. By model reactions it was proved that the 9‐phenylfluorenyl cation, formed on irradiation as a main product in the early stage of the photolysis, takes part in the regeneration of (C6H5)3C+. The changes in electronic spectra, as well as the composition of the reaction mixtures after photolysis and the model reactions, confirm some stages of the earlier proposed scheme.