1967
DOI: 10.1071/ch9671571
|View full text |Cite
|
Sign up to set email alerts
|

Tritertiary arsine complexes of titanium(IV) and zirconium(IV) halides

Abstract: Compounds formed by the tritertiary arsine ligand methylbis(3-dimethyl- arsinylpropyl)arsine (tas) with titanium tetrahalides (where the halide is F, Cl, Br, or I) and zirconium tetrabromide are described. Titanium and zirconium tetrabromide yield isomorphous crystals of the neutral diamagnetic complexes (MBr4 tas), which are believed to be seven- coordinate, The complexes [(TiF4)3 tas], [(TiCl4)2 tas], and [TiI3 tas]I have been isolated and their physical properties and possible structures are discussed.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1

Citation Types

0
3
0

Year Published

1972
1972
2004
2004

Publication Types

Select...
3
2
1

Relationship

0
6

Authors

Journals

citations
Cited by 6 publications
(3 citation statements)
references
References 0 publications
0
3
0
Order By: Relevance
“…Cl( 1)-Ti(1)-Cl( 3) Cl( 2)-Ti(1)-Cl( 3) Cl(3)-Ti(1)-Cl( 4) Se( 1)-Ti(1)-Cl( 1) Se (1)-Ti(1)-Cl(3) Se(2)-Ti(1)-Cl(1) Se(2)-Ti(1)-Cl(3) Cl(1)-Ti(1)-Cl(2) 2.727(1) 2.239(2) 2.267 (2) 163.11 (7) 93.14 (6) 94.87( 6) 87.20( 5) 80.74( 5) 84.41 (5) 81.00(4) 94.94( 6)…”
Section: Reaction Of Ticlmentioning
confidence: 99%
See 2 more Smart Citations
“…Cl( 1)-Ti(1)-Cl( 3) Cl( 2)-Ti(1)-Cl( 3) Cl(3)-Ti(1)-Cl( 4) Se( 1)-Ti(1)-Cl( 1) Se (1)-Ti(1)-Cl(3) Se(2)-Ti(1)-Cl(1) Se(2)-Ti(1)-Cl(3) Cl(1)-Ti(1)-Cl(2) 2.727(1) 2.239(2) 2.267 (2) 163.11 (7) 93.14 (6) 94.87( 6) 87.20( 5) 80.74( 5) 84.41 (5) 81.00(4) 94.94( 6)…”
Section: Reaction Of Ticlmentioning
confidence: 99%
“…2.308(2) 2.744(1) 2.231 (2) 96.42( 7) 109.28 (7) 74.42(3) 162.48 (6) 87.69( 5) 88.46(5) 162.05 (6) Table 5 Selected bond lengths (Å) and angles (Њ) for 1) Ti( 1)-S( 2) Ti( 1)-Cl( 2) Cl( 2)-Ti(1)-Cl( 3) Cl( 2)-Ti(1)-Cl( 5) Cl( 2)-Ti(1)-S( 1) Cl( 2)-Ti(1)-S( 2) Cl(3)-Ti(1)-Cl( 5) Cl(3)-Ti(1)-S( 2) Cl( 5)-Ti(1)-S( 1) Cl( 5)-Ti(1)-S(2) 2.653(2) 2.624(2) 2.300 (2) 160.80 (7) 96.79( 7) 77.82( 6) 87.94( 6) 94.12( 7) 78.80( 6) 90.92( 6) 169.18 (7) Ti( 1)-Cl( 3) Ti(1)-Cl( 5) Ti( 1 6) 165.39 (7) 86.40( 5) 95.27( 6) 86.28( 6) 97.66( 6) 180.00 102.77 (6) longer than those observed in the mononuclear species above. Related oxo-bridged dinuclear Ti species are known, e.g.…”
Section: Reaction Of Ticlmentioning
confidence: 99%
See 1 more Smart Citation