Tris(triphenylphosphine)(trifluorophosphine)rhodium(I) hydride benzene solvate

Neue σ‐Liganden für Übergangsmetalle sind das neutrale Heteroboran [HCo(1,2‐closo‐P2B10H10)2(PEt3)2] (1, links) und das neutrale Metallaheteroboran μ‐[1,2‐{HRu(p‐cymol)}2‐7′,8′‐nido‐P2B9H9]‐3‐(p‐cymol)‐3,1,2‐closo‐RuP2B9H9 (2, rechts). In 1 koordiniert der P2B10H10‐Ligand über ein P‐Atom an Co, und in 2 agieren der closo‐RuP2B9‐ und der nido‐P2B9‐Käfig als κP:κP′‐Brückenliganden.

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Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

McLellan

Ellis

Rosair

et al. 2011

Angewandte Chemie

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Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

et al. 2011

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Structures of HRh(PMe2Ph)4 and HRh(PPh2Me)4

Zhao¹,

Bau²

1998

Inorganica Chimica Acta

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Tris(triphenylphosphine)(trifluorophosphine)rhodium(I) hydride benzene solvate

Cited by 8 publications

References 5 publications

Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

Structures of HRh(PMe2Ph)4 and HRh(PPh2Me)4

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