Tribological Performance of Ionic Liquids Bearing Hydroxyl Groups as Lubricants in the Aluminum-on-Steel Contacts

Abstract

A series of room temperature ionic liquids bearing hydroxyl groups, namely 1-(3’-hydroxyl-n-propyl)-3-alkylimidazolium tetrafluoroborate or hexafluorophosphate, were prepared and characterized. Their typical physical properties were also determined. The tribological test results show that these ionic liquids possess better friction-reducing and anti-wear ability for aluminum-on-steel system than lubricant X-1P. The friction coefficients of them are little higher than that of the nonfunctionlized ionic liquid LP308, while they possess better anti-wear abilities than the latter, which may ascribe to the chemical activity of hydroxyl group. Both the anions and the side substituted alkyl chains attached to the imidazolium cations affect the tribological performance of the lubricants. The SEM, EDS and XPS analysis of the worn surfaces show that complicated tribo-chemical reactions were involved in the sliding process. The boundary films composed of fluorides, nitrogen oxide, BN, and FePO4 were generated on the rubbing aluminum surfaces, which contribute to effectively decreasing the friction and wear of the contacts.

Excellent Lubricating Properties of Ionic Liquid – Myth or Truth

“…Li [20] used another function, namely a hydroxyl group, on the cation. In the end, they obtained almost equal results as Zhu and colleagues.…”

Estudio del comportamiento tribológico y de las interacciones de superficie de nuevos nanofluidos iónicos

“…Por otro lado, se ha estudiado [243] una serie de RTILs con grupos hidroxilo, las tetrafluoroboratos y hexafluorofosfatos de 1(3'-hidroxil-n-propil)3-alquilimidazolio, y se ha demostrado que producen una mayor reducción de la fricción y tienen mejores propiedades anti-desgaste para los contactos acero/aluminio que el lubricante habitualmente utilizado, el X1-P. Esto puede deberse a la actividad química del grupo hidroxilo que genera reacciones triboquímicas que producen películas de fluoruros, óxidos de nitrógeno, BN y FePO 4 , que actúan disminuyendo la fricción y el desgaste.…”