The dry sliding behaviors of titanium silicon carbide (Ti 3 SiC 2 ) against Ni-Cr and Ni-Cr-Ti alloys from ambient temperature up to 600°C were investigated. The tribological performance of Ti 3 SiC 2 depends largely on counterface materials. Fracture and pullout of Ti 3 SiC 2 grains followed by mechanical mix led to poor tribological property for Ti 3 SiC 2 /Ni-Cr alloy tribo-pair. However, for Ti 3 SiC 2 /Ni-Cr-Ti alloy tribo-pair, the oxides film of Ti on Ni-Cr-Ti alloy was effective to reduce friction coefficient and enhance wear resistance.