“…Char ac ter is tic fea tures of this time were profound per tur ba tions in the global biogeochemical cy cle, an increase in at mo spheric CO 2 con tent, global green house warming, and mass ex tinc tion. The Tri as sic-Ju ras sic bound ary (TJB) is char ac ter ized by pro nounced neg a tive ex cur sions in ma rine and ter res trial car bon iso tope re cords (e.g., Pálfy et al, 2001;Hesselbo et al, 2002;Guex et al, 2004;Ward et al, 2004;Galli et al, 2005;Williford et al, 2007;Ruhl et al, 2009;Deenen et al, 2010;White side et al, 2010;Pieñkowski et al, 2012) as well as per tur ba tions to other iso to pic sys tems (Co hen andCoe, 2002, 2007;Kuroda et al, 2010;Callegaro et al, 2012;Pieñkowski et al, 2012) . A ma jor Late Rhaetian "ini tial" neg a tive C iso tope ex cur sion (ini tial CIE) is usu ally sep a rated from a sub se quent long-term Hettangian "main" neg a tive C isotope ex cur sion (main CIE) by a dis tinct pos i tive shift in d 13 C values (Hesselbo et al, 2002(Hesselbo et al, , 2007Schootbrugge et al, 2008;Korte et al, 2009;Pieñkowski et al, 2012;Fig.…”