Oily water purification, immiscible
solvent separation,
sensitive
microreaction, and CO2 blockage are of great interest because
of their importance for the environment and demands of controllable
microreactions. However, one specific material that can meet all the
requirements has yet to be reported. Herein, we developed a simple
environment-benign method to prepare specific dual superlyophobic
materials to solve the problems mentioned earlier. The dual superlyophobic
materials can maintain their dual superoleophobicity in various oil/water
systems, and no additional surface modifications were required when
the oil/water system was changed. Moreover, the materials can be used
to separate oil/water mixtures with separation efficiencies greater
than 99.50% even after 40 separation cycles and separate immiscible
organic solvents with efficiencies over than 99.25% after 20 cycles.
Separations of meal waste oily water at 60 °C and crude oil/water
were also successfully performed. The materials can be further applied
to manipulate and block CO2 bubbles under liquid. The materials
can also act as a platform for microdrop manipulation/microreaction
under liquid.