Energy storage in building envelopes can be accomplished by means of sensible and latent heat accumulation. Latent heat storage using PCMs has been the focus of multiple building studies, due to its relatively high thermal energy storage capacity per volume, compared to sensible storage available in conventional construction materials. PCM-enhanced building envelopes are widely considered as a prospective building enclosure technology which can help in the near future in peak-hour load reductions and cutting of HVAC energy consumption. Currently, there is a great variety of commercially available PCM products that vary in PCM types (salts, paraffins, fatty acids, etc.) and in packaging and encapsulation options (i.e., PCM pouches, containers, macro-and microencapsulation). In addition, PCMs can be differentiated based on their melting temperatures, which together with PCM location and its quantity, are essential for designing of PCM building envelope applications.Most typically, PCMs used in building envelope applications, need to go through a complete phase transition during 24-h time periods in order to be fully effective. This is why it is critical that the temperature in the location where PCM is installed fluctuates (possibly daily) above and below the PCM functional temperature range. As depicted in Fig. 6.1, the PCM functional temperature range starts usually at the lowest temperature limit of the solidification process. Similarly, it ends at the highest temperature of the melting process.Ideally, the entire heat transported should be available at approximately the same temperature for both, melting and solidification processes. However, in real live, this situation only occurs for the paraffinic PCMs. That is why, for well-designed PCM systems, it is crucial that this temperature range be as narrow as possible. One of the complications is an existence of the temperature hysteresis between PCM melting and solidification. Figure 6.1 depicts a situation when the melting point of a PCM-enhanced material is well above its solidification point. In addition, in most of inorganic and some organic PCMs the supercooling effect can be observed.