Trash to treasure: Carbon-free ZnSe derived from waste zinc foil as a high-rate and long-life anode material enabling fast-charging sodium-ion batteries
“…SEM images of the NiSe electrode after 10 and 50 cycles show that the size is not drastically changed and the morphology can be maintained. The stable structure can accomplish a long-cycle life during the repeated (de)embedding of Na + …”
Section: Resultsmentioning
confidence: 99%
“…The stable structure can accomplish a long-cycle life during the repeated (de)embedding of Na + . 37 CVs performed at different sweep speeds provide a detailed explanation for the exceptional rate capability of NiSe-850°C-4 h. Evidently, CVs exhibit comparable contours in Figure 4a, demonstrating decent reaction kinetics throughout the charge−discharge procedures. 38 The specific pseudocapacitive contribution ratio can be quantified by the dependence of the peak current on the sweeping speed.…”
Ni-based selenide has flourished as one of the most competitive anode materials for sodium-ion batteries due to its low cost, wide source, and high theoretical specific capacity. As one of the members, NiSe microparticles with the sizes of 2.0−10.6 μm are synthesized with disused nickel foam fragments by a facile and rapid one-step selenization method, possessing a prominent rate capability of 304.3 mAh g −1 at 15 A g −1 and a remarkable lifespan with 291.7 mAh g −1 after 1600 cycles at 2 A g −1 . A Na 3 V 2 (PO 4 ) 2 F 3 @reduced graphene oxide//NiSe full cell also exhibits excellent sodium storage behavior and potential utility, achieving the largest power density of 1919.0 W Kg −1 , the highest energy density of 146.0 Wh kg −1 , and a capacity of 119.7 mAh g −1 after 600 cycles at 1 A g −1 accompanied by impressive Coulombic efficiency (>95%, except for the first two cycles). The reversible phase transition, proper use of the ether electrolyte, low electrochemical impedance, and favorable structural stability all synergistically contribute to the satisfactory electrochemical property of NiSe. This work effectively improves the preparation efficiency of NiSe, tendering a new synthetic route for the anode materials.
“…SEM images of the NiSe electrode after 10 and 50 cycles show that the size is not drastically changed and the morphology can be maintained. The stable structure can accomplish a long-cycle life during the repeated (de)embedding of Na + …”
Section: Resultsmentioning
confidence: 99%
“…The stable structure can accomplish a long-cycle life during the repeated (de)embedding of Na + . 37 CVs performed at different sweep speeds provide a detailed explanation for the exceptional rate capability of NiSe-850°C-4 h. Evidently, CVs exhibit comparable contours in Figure 4a, demonstrating decent reaction kinetics throughout the charge−discharge procedures. 38 The specific pseudocapacitive contribution ratio can be quantified by the dependence of the peak current on the sweeping speed.…”
Ni-based selenide has flourished as one of the most competitive anode materials for sodium-ion batteries due to its low cost, wide source, and high theoretical specific capacity. As one of the members, NiSe microparticles with the sizes of 2.0−10.6 μm are synthesized with disused nickel foam fragments by a facile and rapid one-step selenization method, possessing a prominent rate capability of 304.3 mAh g −1 at 15 A g −1 and a remarkable lifespan with 291.7 mAh g −1 after 1600 cycles at 2 A g −1 . A Na 3 V 2 (PO 4 ) 2 F 3 @reduced graphene oxide//NiSe full cell also exhibits excellent sodium storage behavior and potential utility, achieving the largest power density of 1919.0 W Kg −1 , the highest energy density of 146.0 Wh kg −1 , and a capacity of 119.7 mAh g −1 after 600 cycles at 1 A g −1 accompanied by impressive Coulombic efficiency (>95%, except for the first two cycles). The reversible phase transition, proper use of the ether electrolyte, low electrochemical impedance, and favorable structural stability all synergistically contribute to the satisfactory electrochemical property of NiSe. This work effectively improves the preparation efficiency of NiSe, tendering a new synthetic route for the anode materials.
“…2j proves the coexistence and uniform distribution of elements Mo, O, S, C and N, thus demonstrating high agreement with its chemical components. 50,52 Based on the CHN elemental analysis report, the overall contents of C and N in the a-MoO 2 / MoS 2 @NC hybrid material was estimated to be 15.36 and 3.46 wt%, respectively, as depicted in Table S1 (ESI †). In principle, the carbonaceous matrix can not only modify the electronic conductivity of the hybrid electrode but also provide an effective buffering space for structural changes upon cycling, thus ensuring high electrochemical activity.…”
Section: Resultsmentioning
confidence: 99%
“…S11 (ESI †), with the decrease of the operating temperature, the ionic conductivity of the electrolyte decreases from 7.086 mS cm −1 (25 °C) to 1.138 mS cm −1 (−40 °C), mainly originating from the low operating temperature induced high viscosity and sluggish diffusion kinetics. 52 In spite of the decreased ionic conductivity, the electrolyte still remained in the liquid state at −40 °C, thus guaranteeing the reversible electrochemical redox upon sodium storage. 38 As expected, a stable cycling performance can be still obtained for the a-MoO 2 /MoS 2 @NC electrode at 0 °C (Fig.…”
The restricted interfacial kinetics, increased charge-transfer resistance, and low diffusion coefficient account for the unsatisfied electrochemical performances of sodium-ion batteries at low temperatures. The commonly used anode materials are crystalline,...
“…[1][2][3][4][5][6] The utilization of organic electrolytes in LIBs results in environmental pollution and safety issues, therefore limiting their widespread use in grid energy storage. 7,8 The consideration of cost and safety has prompted researchers to develop green, low-cost, high-safety, and sustainable energy storage devices. Aqueous zinc-ion batteries (ZIBs) have been recognized as highly appealing alternatives for large-scale energy storage owing to the impressive capacities of nearly 820 mA h g −1 , the low redox potential of −0.76 V, and available supplies of Zn.…”
Zn0.99V5O12·nH2O nanoribbons deliver a low decay ratio of 0.000687% per cycle at 5 A g−1 over 15 000 cycles due to low charge transfer resistance, high DZn2+, high capacitive contribution, and excellent reversible phase transition.
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