Trapping of soluble, KCl-stabilized Cu(<scp>i</scp>) hydrides with CO<sub>2</sub> gives crystalline formates

Grasruck, Alexander; Parla, Giorgio; Lou, Lisha; Langer, Jens; Neiß, Christian; Herrera, Alberto; Frieß, Sybille; Görling, Andreas; Schmid, Günter; Dorta, Romano

doi:10.1039/d3cc03033d

Chem. Commun.

2023

DOI: 10.1039/d3cc03033d

|View full text |Cite

Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO₂ gives crystalline formates

Alexander Grasruck,

Giorgio Parla,

Lisha Lou

et al.

Abstract: Cu(i)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(i)-formates.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite1

Independent1

Authors

Journals

Cited by 2 publications

References 39 publications

(23 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation

Song,

Szymczak

2024

Angewandte Chemie

View full text Add to dashboard Cite

We present a series of borane‐tethered cyclic (alkyl)(amino)carbene (cAAC)‐copper complexes, including a borane‐capped Cu(I) hydride. This hydride is unusually hydridic and reacts rapidly with both CO2 and 2,6‐dimethylphenol at room temperature. Its reactivity is distinct from variants without a tethered borane, and the underlying principles governing the enhanced hydricity were evaluated experimentally and theoretically. These stoichiometric results were extended to catalytic CO2 hydrogenation, and the borane‐tethered (intramolecular) system exhibits ~3‐fold enhancement relative to an intermolecular system.

show abstract

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation

Song,

Szymczak

2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li

Grasruck,

Schall,

Heinemann

et al. 2024

Dalton Trans.

Self Cite

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO₂ gives crystalline formates

Abstract: Cu(i)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(i)-formates.

Cited by 2 publications

References 39 publications

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation

Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li

Contact Info

Product

Resources

About

Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO2 gives crystalline formates

Abstract: Cu(i)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(i)-formates.

Cited by 2 publications

References 39 publications

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO2 Hydrogenation

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO2 Hydrogenation

Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li

Contact Info

Product

Resources

About

Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO₂ gives crystalline formates

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation

Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation