“…Disappearance of the MIF-S signal, and its replacement with a dominant mass-dependent fractionation signal, indicates a rise in ozone, atmospheric oxygen, and marine sulfate concentrations (Farquhar et al, 2000(Farquhar et al, , 2007. Additionally, in the upper Duitschland Formation, shallow-water dolomites record a prominent positive carbon stable isotope excursion of up to +10 ‰ VPDB (Buick et al, 1998;Bekker et al, 2001;Frauenstein et al, 2009;Guo et al, 2009), which may indicate oxygen accumulation due to rapid burial of organic carbon in another part of the basin (Des Marais et al, 1992). Understanding what happened in this interval, between the first 'whiffs' of photosynthetic oxygen production in the Neoarchean and the disappearance of the MIF-S signal in the Paleoproterozoic, is of vital importance for understanding the timing of the GOE Lyons et al, 2014).…”