“…In the last several decades, nitrate leaching through runoff has received growing attention from hydrologists and ecologists, leading to a number of experimental and/or theoretical studies conducted both in forested and agricultural catchments. Therein, the hysteretic nature of the dischargeconcentration relationship and the role of topography, biogeochemistry and hydrological processes in controlling the storage and transport of nutrients have been recognized [e.g., Creed et al, 1996;Band, 1998a, 1998b;Evans and Davies, 1998;Hill et al, 1999;Cvetkovic, 2000, 2002;Porporato et al, 2003;Lindgren et al, 2004Lindgren et al, , 2007Darracq et al, 2005;Rinaldo et al, 2006b;Weiler and McDonnell, 2006;Botter et al, 2006Botter et al, , 2008Darracq and Destouni, 2007]. However, a comprehensive understanding of the variety of connections existing between hydrological processes and solute mobilization at the basin scale is still lacking.…”