Transition metals in organic synthesis: hydroformylation, reduction, and oxidation

Markó, László

doi:10.1016/0022-328x(91)80238-f

Cited by 9 publications

(2 citation statements)

References 589 publications

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“…An increase in the ratio of CO-H 2 from 1 : 1 to 4 : 2 and 5 : 1 decreased the conversions of styrene from 97 to 75 and 28%, respectively (Table 4, entries 1-3). However, the decrease in the CO-H 2 ratio to 2 : 4 and 1 : 5 gave relatively high conversions (92 and 88%) with a slight drop in selectivity to the branched aldehyde B (Table 4, entries 4,5). No products were obtained in the absence of hydrogen (Table 4, entry 6).…”

Section: Hydroformylation Of Styrene Effect Of the Ratio Of Co-hmentioning

confidence: 91%

Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes

Ali

Tijani

Fettouhi

et al. 2005

Applied Organom Chemis

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Active homogeneous catalytic systems based on Rh 6 (CO) 16 -heteropolyacids for the regioselective hydroformylation of styrene and 1-octene and their derivatives have been developed. The effects of the amount and the type of the heteropolyacid have been studied and showed a significant improvement of the conversion of styrene and the selectivity towards branched aldehydes. Other rhodium complexes were also considered in the study and the results showed the advantages of the rhodium cluster Rh 6 (CO) 16

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Section: Hydroformylation Of Styrene Effect Of the Ratio Of Co-hmentioning

confidence: 91%

Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes

Ali

Tijani

Fettouhi

et al. 2005

Applied Organom Chemis

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“…The annealing process is necessary for forming highly ordered morphology of conventional block copolymers. However, annealing sulfonated block copolymers is difficult due to their high glass transition temperature (T g ), which is close to the degradation temperature of the sulfonic acid group (Hegedus,1990;Markó, 1991). When annealing in solution and vapor, the aggregation of ion-exchange groups makes it difficult to process due to the limited solubility of sulfonated block copolymers (Gromadzki et al, 2006).…”

Section: Pems Based On Block Copolymersmentioning

confidence: 99%

Advanced Materials for Polymeric Ultrafiltration Membranes Fabrication and Modification

Muhamad¹,

Nazri²,

Lau³

et al. 2018

Advanced Materials for Membrane Fabrication and Modification

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Regioselectivity Control in the Palladium‐Catalyzed Copolymerization of Propylene with Carbon Monoxide

Batistini

Consiglio

Suter

1992

Angew. Chem. Int. Ed. Engl.

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With 1,3‐propanediylbis(diisopropylphosphine) as ligand L in [Pd(CF3CO2)2L] precatalysts, the strict alternating copolymerization of propylene with carbon monoxide can be carried out with complete regioselectivity and good stereoselectivity. Thus the first synthesis of a regular poly(1‐oxo‐2‐methyltrimethylene) has been achieved. The possible configurations in this polymer are shown below.

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Transition metals in organic synthesis: hydroformylation, reduction, and oxidation

Cited by 9 publications

References 589 publications

Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes

Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes

Advanced Materials for Polymeric Ultrafiltration Membranes Fabrication and Modification

Regioselectivity Control in the Palladium‐Catalyzed Copolymerization of Propylene with Carbon Monoxide

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Transition metals in organic synthesis: hydroformylation, reduction, and oxidation

Cited by 9 publications

References 589 publications

Heteropolyacids enhanced the catalytic activity of Rh6(CO)16 in the hydroformylation of alkenes

Heteropolyacids enhanced the catalytic activity of Rh6(CO)16 in the hydroformylation of alkenes

Advanced Materials for Polymeric Ultrafiltration Membranes Fabrication and Modification

Regioselectivity Control in the Palladium‐Catalyzed Copolymerization of Propylene with Carbon Monoxide

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Product

Resources

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Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes

Heteropolyacids enhanced the catalytic activity of Rh₆(CO)₁₆ in the hydroformylation of alkenes