1999
DOI: 10.1007/bf02467556
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Transition metal complex stationary phases for the CGC analysis of ethers, thioethers and ketones

Abstract: SummaryThe use of polysiloxanes with cyano or thiol groups as stationary phases for complexation gas chromatography is discussed. The polymers were obtained via polycondensation followed by polymerisation of the corresponding dichloro-or dimethoxy-silanes. Both the phases were modified by bonding transition metal chlorides with cyano (CuC12 or COC12) and thiol groups (NiC12 or COC12). The phases were examined in order to determine their application to the analysis of ethers, thioethers and ketones. Due to the … Show more

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Cited by 5 publications
(1 citation statement)
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“…The interactions between the phases and the hydrocarbons are described using the following parameters: retention coefficient (k), retention index (/), molecular retention index (AMe) and specific retention volume (Vg). Results of similar studies obtained for ethers, thioethers, ketones and halogeno-hydrocarbons were discussed in our earlier work [5,6]. …”
Section: Introductionmentioning
confidence: 58%
“…The interactions between the phases and the hydrocarbons are described using the following parameters: retention coefficient (k), retention index (/), molecular retention index (AMe) and specific retention volume (Vg). Results of similar studies obtained for ethers, thioethers, ketones and halogeno-hydrocarbons were discussed in our earlier work [5,6]. …”
Section: Introductionmentioning
confidence: 58%