Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes

Alonso, Diego A.; Nájera, Carmén; Pastor, Isidro M.; Yus, Miguel

doi:10.1002/chem.201000470

Cited by 194 publications

(78 citation statements)

References 152 publications

(97 reference statements)

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“…A c c e p t e d M a n u s c r i p t Edited July 31 26 1,3,5-trimethoxybenzene delivered predominantly 2,6-dimethoxy-p-benzoquinone in both THF and aqueous methanol, 1,2,4-trimethoxybenzene produced a mixture of 2,5-dimethoxy-and 2-methoxy-p-benzoquinone, the ratio of which could be affected by the solvent. Both o-and mdimethoxybenzenes gave 2-methoxy-p-benzoquinone, the m-isomer being significantly more reactive [125].…”

Section: Page 24 Of 96mentioning

confidence: 98%

Recent advances in transition-metal-catalyzed selective oxidation of substituted phenols and methoxyarenes with environmentally benign oxidants

Kholdeeva

Zalomaeva

2016

Coordination Chemistry Reviews

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Section: Page 24 Of 96mentioning

confidence: 98%

Recent advances in transition-metal-catalyzed selective oxidation of substituted phenols and methoxyarenes with environmentally benign oxidants

Kholdeeva

Zalomaeva

2016

Coordination Chemistry Reviews

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“…An alternative has been presented recently by applying homogeneous palladium catalysts for the direct oxidation of aromatic C-H bonds and transformation of aromatic C-X bonds (X = halides). 7 …”

Section: Hydroxylation Of Arenesmentioning

confidence: 99%

Palladium-catalysed hydroxylation and alkoxylation

2011

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The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based catalysts has been extensively studied during recent years. Nowadays it is an established methodology and the success has been proven in manifold synthetic procedures. This tutorial review summarizes the advances on palladiumcatalysed C-O bond formation, means hydroxylation and alkoxylation reactions.

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“…Very recently, the C–H activation has made revolutionary advances in organic synthesis because it allows an access to functionalized products from simple arenes, avoiding their pre-functionalization [8–10]. The synthesis of phenols has greatly benefited from C–H activation, but the application in the synthesis of aryl thiols is still yet to be reported.…”

Section: Introductionmentioning

confidence: 99%

Transition-metal-catalyzed synthesis of phenols and aryl thiols

Liu¹,

Li²,

Yan³

2017

Beilstein J. Org. Chem.

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Phenols and aryl thiols are fundamental building blocks in organic synthesis and final products with interesting biological activities. Over the past decades, substantial progress has been made in transition-metal-catalyzed coupling reactions, which resulted in the emergence of new methods for the synthesis of phenols and aryl thiols. Aryl halides have been extensively studied as substrates for the synthesis of phenols and aryl thiols. In very recent years, C–H activation represents a powerful strategy for the construction of functionalized phenols directly from various arenes. However, the synthesis of aryl thiols through C–H activation has not been reported. In this review, a brief overview is given of the recent advances in synthetic strategies for both phenols and aryl thiols.

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Transition‐Metal‐Catalyzed Synthesis of Hydroxylated Arenes

Abstract: In the Minireview by Alonso, Pastor et. al., the wrong journal was cited in reference [18a], the correct reference is included below. We apologize for this oversight.

Cited by 194 publications

References 152 publications

Recent advances in transition-metal-catalyzed selective oxidation of substituted phenols and methoxyarenes with environmentally benign oxidants

Recent advances in transition-metal-catalyzed selective oxidation of substituted phenols and methoxyarenes with environmentally benign oxidants

Palladium-catalysed hydroxylation and alkoxylation

Transition-metal-catalyzed synthesis of phenols and aryl thiols

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