2010
DOI: 10.1055/s-0030-1258802
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Transition-Metal-Catalyzed Oxidative Cross-Coupling Reactions

Abstract: The oxidative coupling between two nucleophiles using desyl chloride (2-chloro-1,2-diphenylethanone) or molecular oxygen as the oxidant, which just acts as the electron acceptor, is discussed. Various metal reagents were employed as good partners in the oxidative couplings.

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Cited by 14 publications
(3 citation statements)
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“…Column chromatography was performed using the MACHEREY-NAGEL silica gel 60 mit with a mixture of ethyl acetate/hexane or hexane as an eluent. 1 H NMR spectra were recorded on 400 MHz & 600 MHz, 13 C-NMR spectra were recorded on 100 MHz & 151 MHz, and Varian Mercury spectrometer using CDCl3 as solvent. The spectra were recorded and presented as chemical shifts (ppm).…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…Column chromatography was performed using the MACHEREY-NAGEL silica gel 60 mit with a mixture of ethyl acetate/hexane or hexane as an eluent. 1 H NMR spectra were recorded on 400 MHz & 600 MHz, 13 C-NMR spectra were recorded on 100 MHz & 151 MHz, and Varian Mercury spectrometer using CDCl3 as solvent. The spectra were recorded and presented as chemical shifts (ppm).…”
Section: Methodsmentioning
confidence: 99%
“…The di-benzyl core structure is a highly versatile scaffold, offering the potential for the synthesis of a range of compounds in natural products and pharmaceuticals. [1][2][3][4] The most conventional method for obtaining di-benzyl derivatives is reducing carbon-carbon multiple bonds. 5,6 The oxidative homo coupling reaction imposes valuable tools, and the use of oxidizing reagents triggered the transformation of toluene derivatives into dibenzylic compounds.…”
Section: Introductionmentioning
confidence: 99%
“…Coupling reactions can be classified into three types: (I) coupling reactions with electrophiles and nucleophiles, (II) oxidative couplings with nucleophiles, and (III) reductive couplings with electrophiles. 1,2 Oxidative couplings involve cleavage of ubiquitous bonds such as C-H and heteroatom-H bonds in substrates. 3 This characteristic feature realizes more atom-and step-economical transformations than the other coupling reactions.…”
Section: Introductionmentioning
confidence: 99%