Stability is a major issue which explains stable operation of electrical power system. Conventional methods adopted for the enhancement of transient stability (TS) include circuit breakers, fast acting exciters, and reduced total transfer reactance of the system. In this paper, Flexible AC Transmission System (FACTS) controller is used for effective utilization of transmission system. This controller improves the performance of transient stability (TS) and power flow. Simulations are performed to enhance the TS of Western System Coordinating Council (WSCC) 9 bus and 5 bus test systems with fixed compensation on different lines, and the optimal placement has been examined for improved results. For further improving the transient stability margin (TSM), a Thyristor Controlled Series Controller (TCSC) has been employed, and the simulation results show the suitability and effectiveness of TCSC for enhancing TS of power system.