Transformations of peroxide products of olefins ozonolysis

Ishmuratov, G. Yu.; Legostaeva, Yu. V.; Botsman, L. P.; Толстиков, Г. А.

doi:10.1134/s1070428010110011

Cited by 25 publications

(2 citation statements)

References 100 publications

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“…In many cases, rearrangements and related reactions of peroxides are key pathways in laboratory, industrial, and biological processes. The rearrangements of organic peroxides are covered in the literature in hundreds of publications and in several specialized and partial reviews [ 183 – 188 ]. The present review is the first to combine the key data on both, name rearrangements and less well-known rearrangements and related oxidative processes, and to summarize systematically related and different features of these reactions, compares their mechanisms, and assesses the prospects of their application.…”

Section: Introductionmentioning

confidence: 99%

Rearrangements of organic peroxides and related processes

Yaremenko¹,

Vil²,

Demchuk³

et al. 2016

Beilstein J. Org. Chem.

179

136

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SummaryThis review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

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Section: Introductionmentioning

confidence: 99%

Rearrangements of organic peroxides and related processes

Yaremenko¹,

Vil²,

Demchuk³

et al. 2016

Beilstein J. Org. Chem.

179

136

View full text Add to dashboard Cite

show abstract

“…3 The most common substrates for ozonolysis are unsaturated species containing either double or triple carbon-carbon bonds, which are generally ozonised to afford their respective aldehydes/ketones and/or acids. 4 This transformation has great synthetic utility, both in an academic and an industrial setting. Ozone can also be used to oxidise phosphorus 1,5 and sulphur 1,6 -containing compounds as well as organometallics 7 and other inorganic species.…”

Section: Introductionmentioning

confidence: 99%