Transformation of a ditopic Schiff base nickel(II) nitrate complex into an unsymmetrical Schiff base complex by partial hydrolytic degradation: structural and density functional theory studies

Wang, Qiang; Liu, Yang; Gao, Wei; Xu, Zhijun; Li, Yuguang; Li, Wei; Pilkington, Melanie

doi:10.1007/s11243-014-9840-y

Cited by 6 publications

(2 citation statements)

References 27 publications

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“…Salicylidenes are a type of Schiff base derived from the condensation of a primary amine with a salicylaldehyde derivative. Numerous substituents can be placed on the phenol ring, and the imine bridge allows for tuning the size and the shape of the complexes to control their self-assembly on surfaces [9] . A schematic structure can be observed in Fig.…”

Section: Introductionmentioning

confidence: 99%

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Electronic and magnetic properties of the [Ni(salophen)]: An experimental and DFT study

Mendes

Germino

Fazolo

et al. 2018

Journal of Advanced Research

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Section: Introductionmentioning

confidence: 99%

“…A variety of metal ions (diamagnetic and paramagnetic) can be introduced in the coordination site, in most cases forming square planar array frameworks [6] . Schiff base nickel(II) salen-type complexes have been extensively used in catalysis [7] , [9] and for biological purposes [11] .…”

Section: Introductionmentioning

confidence: 99%

Electronic and magnetic properties of the [Ni(salophen)]: An experimental and DFT study

Mendes

Germino

Fazolo

et al. 2018

Journal of Advanced Research

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Electrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrode

2020

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This present study describes a pencil graphite electrode surface covered with Cu(II) and Fe(III) complexes based on Salophen derivative Schiff bases in acetonitrile solution containing LiClO4 as a supporting electrolyte. Cyclic voltammetry method was used for the surface modification procedure with 25 cycle at a sweep rate of 50 mV s−1. Some characterization methods were used to identify of the prepared modified surfaces including cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), Ultraviolet‐visible Spectroscopy (UV‐Vis), and Scanning Electron Microscopy/Energy Dispersive X‐ray Spectroscopy (SEM/SEM‐EDX). The catalytic activity of these modified surfaces on the electrochemical oxidation of catechol (CC) was investigated and they compared with each other. The results demonstrated that these modified electrodes showed perfect electrocatalytic activity on the catechol determination, however the modified electrode prepared with the Cu(II) complex has higher catalytic activity than this prepared with the Fe(III) complex thanks to its the lower detection limit.

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Sonochemical synthesis, characterization, biological applications, and DFT study of new nano-sized manganese complex of azomethine derivative of diaminomaleonitrile

et al. 2019

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Transformation of a ditopic Schiff base nickel(II) nitrate complex into an unsymmetrical Schiff base complex by partial hydrolytic degradation: structural and density functional theory studies

Cited by 6 publications

References 27 publications

Electronic and magnetic properties of the [Ni(salophen)]: An experimental and DFT study

Electronic and magnetic properties of the [Ni(salophen)]: An experimental and DFT study

Electrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrode

Sonochemical synthesis, characterization, biological applications, and DFT study of new nano-sized manganese complex of azomethine derivative of diaminomaleonitrile

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