trans-Dichlorobis(triphenylphosphine)palladium(II)

Ferguson, George; McCrindle, Robert; McAlees, Alan J.; Parvez, Masood

doi:10.1107/s0567740882009583

Cited by 58 publications

(41 citation statements)

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“…The Pd-As bond distance (2.437(1) A) appears to be longer than that measured for the Pd-As bong distance in t r a n~-[ P d C l~( A s P h~)~I , which is reported as 2.42 A (21). Finally, the Pd-Cl bond (2.395(1) A) is longer than tho!e measured for other related systems (2.267(9)-2.326(4) A) (17)(18)(19), in accord with our infrared data (see above).…”

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confidence: 43%

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Cyclopalladation of trimesitylarsine. The X-ray crystal structure for

Alyea¹,

Ferguson²,

Malito³

et al. 1988

Can. J. Chem.

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(1), Pd-P 2.318(1), Pd-C 2.056(3), and Pd-As 2.437(1) A; As-Pd-C196.5(1), CI-Pd-P 90.9(1), P-Pd-C 93.7(1), As-Pd-C 78.9(1), As-Pd-P 172.6(1), and CI-Pd-C 171.7(1)". The average C-P-C angle (104.3(1)") is smaller than expected and is rationalized on the basis of steric effects operative within the complex. Pd-P 2,318(1), Pd-C 2,056(3) et Pd-As 2,437(1) A; As-Pd-C1 96,5(1), CI-Pd-P 90,9(1), P-Pd-C 93,7(1), As-Pd-C 78,9(1), As-Pd-P 172,6(1) et C1-Pd-C 171,7(1)". L'angle C-P-C moyen (104,3(1)") est plus faible que prevu et on rationalise ce fait sur la base d'effets sttriques operant a l'intkrieur du complexe.[Traduit par la revue]

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confidence: 43%

“…1) (17). It is worth noting that the As-C (11) bond distance (1.946(3) A) of the metallated ring is shorter than eithef the As-C (21) or As-C(31) bonds and is shorter than that observed for the As-C bond distance in free A~( m e s )~ (ave6-age 1.976(5) A) (16).…”

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confidence: 81%

Cyclopalladation of trimesitylarsine. The X-ray crystal structure for

Alyea¹,

Ferguson²,

Malito³

et al. 1988

Can. J. Chem.

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“…This field has becomem ultidisciplinary in nature encompassing areasl ikeo rganic synthesis, catalysis, materials sciencea nd photo-physicalc hemistry [1][2][3][4]. Ar ange of crystal structures have been reported for trans-dichloro-bis(triphenylphosphine) palladium(II) complexes, with or without as olvent molecule [5][6][7][8][9]. The asymmetric unit of the title crystal structure consists of one neutral molecule [ (3) 8f 0.5165(9) 0.3701 (7 (11) 8f 0.2828 (9 …”

Section: Discussionmentioning

confidence: 99%

Crystal structure of bis(triphenylphospine-kP)-dichloropalladium( II) —acetonitrile (1:1), [PdCl2(C18H15P)2] · CH3CN

Cui¹,

Li²,

Wen³

et al. 2011

Zeitschrift Für Kristallographie - New Crystal Structures

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“…[11] Completely different from the heterobinuclear Fe-Pt complexes [(CO) 3 Fe(µ-CNR)(µ-dppm)Pt(PPh 3 )] with a bridging isocyanide ligand that has a nearly equal distance to Fe and Pt atoms, [9] the bridging isocyanide ligand in 3a-3d is clearly leaning to the iron center, and the Fe( . [12] complexes with Ni metal. The 1 H NMR spectrum of 4 in CD 3 CN displays one broad signal at δ = 2.59 ppm on account of the Cp* protons.…”

Section: Thementioning

confidence: 99%