2015
DOI: 10.1007/s11356-015-5040-3
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Tracking the behavior of different size fractions of dissolved organic matter in a full-scale advanced drinking water treatment plant

Abstract: In this study, five different dissolved organic matter (DOM) fractions, defined based on a size exclusion chromatography with simultaneous detection of organic carbon (OCD) and ultraviolet (UVD), were quantitatively tracked with a treatment train of coagulation/flocculation-sand filtration-ozonation-granular activated carbon (GAC) filtration in a full-scale advanced drinking water treatment plant (DWTP). Five DOM samples including raw water were taken after each treatment process in the DWTP every month over t… Show more

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Cited by 20 publications
(6 citation statements)
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References 42 publications
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“…Greater abundance of lower molecular weight compounds may contribute to inefficient DOC removal from postfire stormwater due to the hydrophilic nature of the DOM composition compared to higher molecular weight, hydrophobic humic substances. , The DOM sampled in postfire rainstorms had a higher fluorescence index (FI) (Figure ), correlated with a lower molecular weight DOM composition, which is more challenging to remove by coagulation. , Further, the FI values of samples collected from the burned area (water intake) were statistically higher than the reference site (+ 0.038), and higher than prefire data . In a different study, the authors also observed an increase in FI and blue-shifted emission spectra for leachates of soils heated at a moderate temperature (350 °C) .…”
Section: Postfire Variability In Water Treatmentmentioning
confidence: 99%
“…Greater abundance of lower molecular weight compounds may contribute to inefficient DOC removal from postfire stormwater due to the hydrophilic nature of the DOM composition compared to higher molecular weight, hydrophobic humic substances. , The DOM sampled in postfire rainstorms had a higher fluorescence index (FI) (Figure ), correlated with a lower molecular weight DOM composition, which is more challenging to remove by coagulation. , Further, the FI values of samples collected from the burned area (water intake) were statistically higher than the reference site (+ 0.038), and higher than prefire data . In a different study, the authors also observed an increase in FI and blue-shifted emission spectra for leachates of soils heated at a moderate temperature (350 °C) .…”
Section: Postfire Variability In Water Treatmentmentioning
confidence: 99%
“…Despite being very powerful, EEM-PARAFAC can only characterize light-absorbing DOM constituents. This limitation can be alleviated by using size exclusion chromatography (SEC) equipped with an organic carbon detector (SEC-OCD), which further unravels the heterogeneous structures of DOM in terms of molecular sizes (Huber et al 2011, Quang et al 2015. For example, biopolymer, quantified by SEC-OCD, is known to play an important role in membrane fouling potential (Ayache et al 2013, Tian et al 2013.…”
Section: Introductionmentioning
confidence: 99%
“…The adverse effect of heating on the overall treatability of the leachates might be explained by a lower‐molecular‐weight DOM composition (Quang et al, ). Although the DOM was more aromatic following heating, the smaller, nitrogen‐enriched compounds appeared less amenable to coagulation treatment.…”
Section: Resultsmentioning
confidence: 99%
“…Other research suggests that lower‐molecular‐weight DOM leached from heated materials compared with unheated materials (Wang, Dahlgren, & Chow, ). Lower‐molecular‐weight DOM is generally more challenging to remove by conventional treatment processes (Archer & Singer, ; Quang, Choi, & Hur, ; White, Thompson, Harrington, & Singer, ), with implications for finished water quality. Furthermore, an increase in nitrogenous DBP (N‐DBP) precursors has been observed for postfire river samples (Hohner et al, ), wildfire‐affected sediment leachates (Hohner, Terry, Townsend, Summers, & Rosario‐Ortiz, ), and wildfire detritus extracts (Fernández et al, ; Wang, Dahlgren, Erşan, et al, ).…”
Section: Introductionmentioning
confidence: 99%