“…Spherical IMPs, typically produced by coal combustion, are found in fluvial sediments, street dust and urban surface soil (Petrovsky and Ellwood, 1999;Mitchell and Maher, 2009;Wang et al, 2018Wang et al, , 2019. Magnetic measurements that examine the abundance of IMPs, their particle size and mineralogy have been widely used to reflect heavy metal contamination and trace particle sources as a rapid, economic and non-destructive approach (e.g., Maher and Thompson, 1999;Zhang et al, 2011;Chaparro et al, 2017;Ge et al, 2017;Hatfield et al, 2019;Wang et al, 2018Wang et al, , 2019Li et al, 2021). In recent J o u r n a l P r e -p r o o f years, the exposure risk of IMPs themselves, especially for nano-sized particles (<100 nm) has drawn public concerns (Maher et al, 2016;Calderón-Garcidueñas et al 2019;Lu et al, 2020;Liu et al, 2021).…”