doi: 10.7185/geochemlet.1741Tin exists both under the 2+ and 4+ oxidation states in igneous systems, and thus its geochemical behaviour changes as a function of oxygen fugacity. To characterise the redox state of Sn during magmatic differentiation and how this affects its isotope composition, we have measured Sn isotopic and elemental abundances in a suite of samples from the Kilauea Iki lava lake. Sn behaves as a highly incompatible element during fractional crystallisation. Lattice strain modelling shows that Sn 2+ has mineral-melt partition coefficients (D min/melt ) ≈ 1 in plagioclase and clinopyroxene, whereas it is highly incompatible in all phases save for ilmenite, attesting to the sole presence of Sn 4+ in basaltic liquid at the Fayalite-MagnetiteQuartz (FMQ) buffer. Furthermore, Sn isotopes are unfractionated during crystallisation of silicates, but decrease to lighter values upon ilmenite precipitation. Isotopic fractionation is onset by the coordination change between Sn 4+ in the melt (6-to 8-fold) and ilmenite (6-fold). The Sn isotope composition of komatiites, which are high degree, high temperature partial melts are used to estimate the Sn isotope composition of the bulk silicate Earth (BSE). Komatiites have d 122 Sn within the range of the basalts (before ilmenite precipitation) and together provide the best estimate of the BSE of 0.49 ± 0.11 ‰ (2 s.d., n = 9).
LetterModerately volatile elements (MVEs) and their isotopes are important tracers for planetary and nebular processes such as evaporation and condensation (e.g., O'Neill and Palme, 2008;Paniello et al., 2012). A condition that must be met before MVEs can be used to answer these questions is knowledge of the isotopic composition of the bulk silicate Earth (BSE) and hence how their isotopes fractionate during igneous processes.Tin has three oxidation states (Sn 0 , Sn 2+ , Sn 4+ ) that confer differing properties as a function of oxygen fugacity ( fO 2 ). As such, Sn may behave as a siderophile, chalcophile and lithophile element at high temperatures (e.g., Heinrich, 1990;Witt-Eickschen et al., 2009). Although the dependence of Sn 2+ /Sn 4+ on melt composition, and the fO 2 at which this transition occurs in basaltic melts are poorly known (Farges et al., 2006), the behaviour of Sn in igneous systems may be gleaned by comparison with elements of similar incompatibility. Observations of oceanic basalts show that Sn/Sm, Sn/ Zr and Sn/Hf ratios are nearly uniform across MORB and OIB (Jochum et al., 1993;Jenner and O'Neill, 2012). Correlations with tetravalent, incompatible elements suggest Sn may be lithophile and occurs as Sn 4+ during igneous processes near FMQ.At equilibrium, all else being equal, isotopic fractionation is controlled by differences in bond stiffness between two phases (e.g., Schauble, 2004). The diversity in Sn bonding environments (Sn-O, Sn-S and Sn 0 ) combined with differing oxidation states offer scope for significant isotope fractionation. Indeed, Creech et al. (2017) analysed four genetically unrelated igne...