Trace Determination of Organic Compounds in Water by Direct Enrichment in Multichannel Thick Film Silicone Rubber Traps with Capillary Gas Chromatography

Abstract

The application of Multichannel Silicone Rubber Traps for the direct analysis of organic compounds in water was studied. The optimum collection flow rate for a 10 mL sample was found to be ca. 150 μL·min–1. The effect of methanol on the retention power of the trap was evaluated. The addition of a methanol fraction of up to 40% to the water standards did not show any loss in collection efficiency. It was shown that the extraction of organic compounds from water with the multichannel trap is uncomplicated, i. e. methanol is not required to achieve accurate analyses, concentration of the sample onto the trap is by gravity flow, and excess water remaining in the multichannel trap after water extraction is removed by centrifugation. With the use of the multichannel silicone rubber trap a wide boiling point range of compounds were analyzed from aqueous samples at levels of 1–4 μg·L–1.

Determination of PAH in food samples by HPLC with fluorimetric detection following sonication extraction without sample clean-up

“…1,2 Numerous research papers have been published on PAH in environmental samples, such as air, water, marine sediments and soil. [1][2][3][4][5] Although few foods have been analysed to date, PAH have been detected in vegetable oils, fruits, sea food, grilled and roasted meat, smoked fish, tea and coffee. [6][7][8][9][10][11] Food pollution is due to the deposition of PAH from the air or water, or as a result of preservation, drying and cooking procedures.…”

Studies on the Use of Commercial Capillary Gas Chromatographic Columns as Diffusion Denuders

“…In recent years a few papers on the use of pieces of open tubular GC columns for isolation and enrichment of selected analytes from gaseous matrices [4,5,[8][9][10][11][12][13][14][15][16][17] and water [18][19][20][21][22][23][24][25] have been published. Open tubular GC columns have the structural features of a cylindrical denuder.…”