Electromagnetic synergy is a more
effective physical method than
a single AC electric field (ACEF) to enhance oil–water separation.
However, the electrocoalescence behavior of droplets dispersed with
salt ions in oil under the synergistic electromagnetic field (EMSF)
still lacks research. Herein, the evolution coefficient of liquid
bridge diameter (C
1) characterizes the
growth rate of the liquid bridge diameter, a series of Na2CO3-dispersed droplets with different ionic strengths
were prepared, and C
1 values of droplets
under ACEF and EMSF were compared. Micro high-speed experiments revealed
that C
1 under ACEF is larger than C
1 under EMSF. In particular, when σ =
100 μS·cm–1and E = 629.73
kV·m–1, C
1 under
the ACEF is 15% larger than C
1 under EMSF.
Additionally, the theory of ion enrichment is put forward, which explains
the influence of salt ions on ζ potential and total surface
potential in EMSF. This study provides guidance for designing high-performance
devices by introducing electromagnetic synergy in water-in-oil emulsion
treatment.