Towards sustainable green diesel fuel production: Advancements and opportunities in acid-base catalyzed H2-free deoxygenation process

Asikin-Mijan, N.; Juan, J.C.; Taufiq-Yap, Y.H.; Ong, Hwai Chyuan; Lin, Yu-Chuan; AbdulKareem-Alsultan, G.; Lee, H.V.

doi:10.1016/j.catcom.2023.106741

Cited by 10 publications

(1 citation statement)

References 119 publications

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“…The presence of a high amount of acid site in the surface of Ni/RHA may responsible for its high conversion of oleic acid. The presence of acid sites is important in deoxygenation of fatty acids for removal of oxygen in fatty acids via C-O cleavage reaction (Asikin-Mijan et al, 2023). However, the presence of strong acid sites may lead to severe cracking of produced hydrocarbon into shorter hydrocarbon chain with low boiling point.…”

Section: Catalytic Performancementioning

confidence: 99%

Effect of various silica-supported nickel catalyst on the production of bio-hydrocarbons from oleic acid

Riyandi,

Rinaldi,

Yunarti

et al. 2024

Int. J. Renew. Energy Dev.

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The conversion of fatty acids into bio-hydrocarbons can be carried out through a deoxygenation (DO) reaction. Catalytic deoxygenation of fatty acids can occur through three reaction pathways: decarbonylation, decarboxylation, and hydrodeoxygenation. In this study, three kinds of silica were prepared: (i) silica obtained from the rice husk ash (RHA); (ii) synthetic mesoporous silica SBA-16; and (iii) commercial silica. All prepared silica was used as supported nickel (Ni) catalyst for bio-hydrocarbon production through DO reaction of oleic acid. The objective of this study was to investigate the effect of variations of silica on the reaction pathway and final products composition of DO reaction of oleic acid. The catalysts were characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), surface area analysis, and NH3-temperature-programme desorption. Based on XRF and XRD analysis results, it can be concluded that nickel was successfully impregnated into all silica. All samples of catalysts were used in a reaction carried out at temperature of 285 °C under a pressure of 40 bar H2 for 2h. The results showed that all catalysts were able to convert oleic acid to bio-hydrocarbon with differences in products composition. The highest oleic acid conversion of 98.25% was achieved with Ni/RHA catalyst but the obtained liquid products was the lowest among other catalysts. It is found that this phenomenon was closely related to the acidity properties of the catalyst.

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Section: Catalytic Performancementioning

confidence: 99%