Towards Multi-Functional SiO2@YAG:Ce Core–Shell Optical Nanoparticles for Solid State Lighting Applications

Abstract

This paper aims to investigate the synthesis, structure, and optical properties of SiO2@YAG:Ce core–shell optical nanoparticles for solid state lighting applications. YAG:Ce phosphor is a key part in white light emitting diodes (LEDs), with its main functionality being the generation of yellow light. Generated yellow light from phosphor will be combined with blue light, emitted from chip, resulting in the generation of white light. Generated light in LEDs will often be scattered by SiO2 nanoparticles. SiO2 nanoparticles are often distributed within the optical window, aiming for a more homogeneous light output. The main idea in this research is to combine these functionalities in one core–shell particle, with its core being SiO2 and its shell being phosphor. In this study core–shell nanoparticles with different Ce3+ concentrations were synthesized by a sol–gel method. Synthesized nanoparticles were characterized by X-ray diffraction (XRD), small angle X-ray scattering (SAXS) analysis, high resolution transmission electron macroscopy (HRTEM), Fourier transform infrared (FTIR), and photoluminescence spectroscopy. Luminescence characteristics of SiO2@YAG:Ce core–shell particles were compared with that of SiO2/YAG:Ce mixture composite, which is now used in commercial LEDs. Obtained results showed that core–shell nanoparticles have comparatively much better optical properties, compared to SiO2/YAG:Ce mixture composite and can therefore be potentially used in LEDs.

Facile Synthesis of Ag Nanowire/TiO2 and Ag Nanowire/TiO2/GO Nanocomposites for Photocatalytic Degradation of Rhodamine B

“…These transformations happen as a result of electron-hole pair formation. The energy, required to create electron-hole pairs, is provided by light radiation, which is often UV light [6,7]. The photo-generated electrons react with O 2 , resulting in the generation of active anion radicals, such as O •2− .…”

Heterojunction of Pores in Granola‐Type Crystals of Two Different Metal–Organic Frameworks for Enhanced Formaldehyde Removal

“…In previous studies, MOFs were combined with different organic/inorganic nanoparticles to obtain heterogeneous structures (20)(21)(22)(23)(24)(25)(26)(27)(28)(29)(30), but these studies focus on combining MOFs with other class of functional materials. Different pores of MOFs have been previously incorporated by impregnating either different organic linkers or metal oxide units (31)(32)(33)(34)(35), defects (12,36,37), and meso/macropores (38,39), as well as by coating MOFs with other MOFs (40)(41)(42).…”