2020
DOI: 10.1039/d0ra08143d
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Toward the synthesis, fluorination and application of N–graphyne

Abstract: The appearance of PTFE-like nanochains in the structure of fluorinated N–graphyne strongly influences both electrochemical and biological properties.

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Cited by 8 publications
(3 citation statements)
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References 49 publications
(72 reference statements)
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“…Furthermore, the theoretically estimated band gap of the AB stack-1 configuration was consistent with the experimental value. The experimentally determined band gap of randomly fluorinated triazine-based graphyne by XeF 2 , reported by Szczurek et al, ranged from 3.12 to 3.34 eV and grew with increasing fluorine concentration [ 150 ]. An increase in the band gap upon the fluorination of acetylenic bridges is consistent with the decoupling of benzenic chromophores.…”
Section: Electronic Propertiesmentioning
confidence: 99%
“…Furthermore, the theoretically estimated band gap of the AB stack-1 configuration was consistent with the experimental value. The experimentally determined band gap of randomly fluorinated triazine-based graphyne by XeF 2 , reported by Szczurek et al, ranged from 3.12 to 3.34 eV and grew with increasing fluorine concentration [ 150 ]. An increase in the band gap upon the fluorination of acetylenic bridges is consistent with the decoupling of benzenic chromophores.…”
Section: Electronic Propertiesmentioning
confidence: 99%
“…71 Szczurek and co-workers developed a route toward the structure of N-graphyne via the Sonogashira cross-coupling reaction of 1,3,5-triethynylbenzene with cyanuric chloride. 72 In addition to the 2D film morphology, Chi and co-workers reported the synthesis of well-aligned nitrogen-doped GDYNW on gold surfaces with selective on-surface acetylenic homocou- pling reactions (Figure 4a−d). 73 Li and co-workers presented the synthesis of GDY nanoribbons with uniform width (4.16 nm in width; Figure 4e−g) through stepwise inter-and intramolecular Glaser−Hay coupling reaction of ethynyl groups.…”
Section: Synthesis Of Few-layer Graphdiynementioning
confidence: 99%
“…Kan et al explored the interfacial synthesis of 2D N-graphdiyne films . Szczurek and co-workers developed a route toward the structure of N-graphyne via the Sonogashira cross-coupling reaction of 1,3,5-triethynylbenzene with cyanuric chloride …”
Section: Synthesis Of Graphdiyne and Its Derivativesmentioning
confidence: 99%