Toward the synthesis, fluorination and application of N–graphyne

Abdi, Gisya; Filip, Anna; Krajewski, Michał; Kazimierczuk, Krzysztof; Strawski, Marcin; Szarek, Paweł; Hamankiewicz, Bartosz; Mazej, Zoran; Cichowicz, Grzegorz; Leszczyński, Piotr J.; Fijałkowski, Karol J.; Szczurek, Andrzej

doi:10.1039/d0ra08143d

Cited by 8 publications

(3 citation statements)

References 49 publications

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“…Furthermore, the theoretically estimated band gap of the AB stack-1 configuration was consistent with the experimental value. The experimentally determined band gap of randomly fluorinated triazine-based graphyne by XeF 2 , reported by Szczurek et al, ranged from 3.12 to 3.34 eV and grew with increasing fluorine concentration [ 150 ]. An increase in the band gap upon the fluorination of acetylenic bridges is consistent with the decoupling of benzenic chromophores.…”

Section: Electronic Propertiesmentioning

confidence: 99%

Developments in Synthesis and Potential Electronic and Magnetic Applications of Pristine and Doped Graphynes

et al. 2021

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Doping and its consequences on the electronic features, optoelectronic features, and magnetism of graphynes (GYs) are reviewed in this work. First, synthetic strategies that consider numerous chemically and dimensionally different structures are discussed. Simultaneous or subsequent doping with heteroatoms, controlling dimensions, applying strain, and applying external electric fields can serve as effective ways to modulate the band structure of these new sp2/sp allotropes of carbon. The fundamental band gap is crucially dependent on morphology, with low dimensional GYs displaying a broader band gap than their bulk counterparts. Accurately chosen precursors and synthesis conditions ensure complete control of the morphological, electronic, and physicochemical properties of resulting GY sheets as well as the distribution of dopants deposited on GY surfaces. The uniform and quantitative inclusion of non-metallic (B, Cl, N, O, or P) and metallic (Fe, Co, or Ni) elements into graphyne derivatives were theoretically and experimentally studied, which improved their electronic and magnetic properties as row systems or in heterojunction. The effect of heteroatoms associated with metallic impurities on the magnetic properties of GYs was investigated. Finally, the flexibility of doped GYs’ electronic and magnetic features recommends them for new electronic and optoelectronic applications.

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Section: Electronic Propertiesmentioning

confidence: 99%

Developments in Synthesis and Potential Electronic and Magnetic Applications of Pristine and Doped Graphynes

et al. 2021

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“…71 Szczurek and co-workers developed a route toward the structure of N-graphyne via the Sonogashira cross-coupling reaction of 1,3,5-triethynylbenzene with cyanuric chloride. 72 In addition to the 2D film morphology, Chi and co-workers reported the synthesis of well-aligned nitrogen-doped GDYNW on gold surfaces with selective on-surface acetylenic homocou- pling reactions (Figure 4a−d). 73 Li and co-workers presented the synthesis of GDY nanoribbons with uniform width (4.16 nm in width; Figure 4e−g) through stepwise inter-and intramolecular Glaser−Hay coupling reaction of ethynyl groups.…”

Section: Synthesis Of Few-layer Graphdiynementioning

confidence: 99%

“…Kan et al explored the interfacial synthesis of 2D N-graphdiyne films . Szczurek and co-workers developed a route toward the structure of N-graphyne via the Sonogashira cross-coupling reaction of 1,3,5-triethynylbenzene with cyanuric chloride …”

Section: Synthesis Of Graphdiyne and Its Derivativesmentioning

confidence: 99%

Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

Zheng

Chen

et al. 2023

ACS Nano

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Graphdiyne (GDY), a rising star of carbon allotropes, features a two-dimensional all-carbon network with the cohybridization of sp and sp 2 carbon atoms and represents a trend and research direction in the development of carbon materials. The sp/sp 2 -hybridized structure of GDY endows it with numerous advantages and advancements in controlled growth, assembly, and performance tuning, and many studies have shown that GDY has been a key material for innovation and development in the fields of catalysis, energy, photoelectric conversion, mode conversion and transformation of electronic devices, detectors, life sciences, etc. In the past ten years, the fundamental scientific issues related to GDY have been understood, showing differences from traditional carbon materials in controlled growth, chemical and physical properties and mechanisms, and attracting extensive attention from many scientists. GDY has gradually developed into one of the frontiers of chemistry and materials science, and has entered the rapid development period, producing large numbers of fundamental and applied research achievements in the fundamental and applied research of carbon materials. For the exploration of frontier scientific concepts and phenomena in carbon science research, there is great potential to promote progress in the fields of energy, catalysis, intelligent information, optoelectronics, and life sciences. In this review, the growth, self-assembly method, aggregation structure, chemical modification, and doping of GDY are shown, and the theoretical calculation and simulation and fundamental properties of GDY are also fully introduced. In particular, the applications of GDY and its formed aggregates in catalysis, energy storage, photoelectronic, biomedicine, environmental science, life science, detectors, and material separation are introduced.

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State, synthesis, perspective applications, and challenges of Graphdiyne and its analogues: A review of recent research

Hayat

Sohail

Javid

et al. 2023

Advances in Colloid and Interface Science

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Toward the synthesis, fluorination and application of N–graphyne

Abstract: The appearance of PTFE-like nanochains in the structure of fluorinated N–graphyne strongly influences both electrochemical and biological properties.

Cited by 8 publications

References 49 publications

Developments in Synthesis and Potential Electronic and Magnetic Applications of Pristine and Doped Graphynes

Developments in Synthesis and Potential Electronic and Magnetic Applications of Pristine and Doped Graphynes

Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

State, synthesis, perspective applications, and challenges of Graphdiyne and its analogues: A review of recent research

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