Toughening of POSS–MPS composites with low dielectric constant prepared with structure controllable micro/mesoporous nanoparticles

Shao, Yudi; Huang, Fenchao; Wang, Jia; Wu, Zhenzhen

doi:10.1039/c8ra07430e

Cited by 12 publications

(4 citation statements)

References 29 publications

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“…For example, many studies have reported on the incorporation of caged polyhedral oligomeric silsesquioxane (POSS) hollow nanoparticles into polymers to prepare low-k nanohybrid materials. [13][14][15][16][17][18][19] However, the obvious limitations such as small size, high-cost and difficulty to synthesize prevent further applications for functionalized POSS monomers. To overcome this limitation, several research groups used inorganic nano-mesoporous silica materials such as MCM-41 and hollow silica spheres as fillers to greatly reduce the k value of silica-based nanocomposites.…”

Section: Introductionmentioning

confidence: 99%

An ultralow-k dielectric derived from a fluorinated polybenzoxazole composite film with yolk–multishell mesoporous silica nanostructures

Zhuang

Zhang

et al. 2023

J. Mater. Chem. C

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Section: Introductionmentioning

confidence: 99%

An ultralow-k dielectric derived from a fluorinated polybenzoxazole composite film with yolk–multishell mesoporous silica nanostructures

Zhuang

Zhang

et al. 2023

J. Mater. Chem. C

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“…Unfortunately, the latter improvement is often achieved at the expense of thermal stability. This deficiency is remedied by the synthesis of nanocomposites of CER with montmorillonite (MMT) [ 35 , 36 , 37 , 38 , 39 , 40 ], carbon nanotubes [ 41 , 42 ], nanostructured aluminum borate [ 43 ], ZnO [ 44 ], ZrW 2 O 8 [ 45 ], nanosilica [ 46 , 47 , 48 ], polyhedral oligomeric silsesquioxane (POSS) [ 49 , 50 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 67 , 68 , 69 , 70 , 71 , 72 , 73 ], and other nanofillers. The most pronounced effect on mechanical and thermal properties of CERs is achieved when nanoparticles with organically modified surface are used, as they may react with polymer networks.…”

Section: Introductionmentioning

confidence: 99%

“…In the case of reactive R, 3-D POSS molecules with diameters of 1–2 nm, they may graft chemically to polymer structures. New hybrid organic–inorganic CER-based thermosets with hydroxyl- [ 49 , 51 , 52 , 55 , 69 , 72 ], amino- [ 50 , 53 ], epoxy- [ 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 68 , 69 , 70 ], cyanate- [ 67 ], benzoxazinyl- [ 71 ] or methacrylate-functionalized [ 73 ] POSS units have thus been obtained with improved thermal and mechanical properties.…”

Section: Introductionmentioning

confidence: 99%

Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites

Grigoryeva,

Fainleib,

Starostenko

et al. 2023

Polymers

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Nanocomposites of cyanate ester resin (CER) filled with three different reactive amino-functionalized polyhedral oligomeric silsesquioxane (POSS) were synthesized and characterized. The addition of a small quantity (0.1 wt.%) of amino-POSS chemically grafted to the CER network led to the increasing thermal stability of the CER matrix by 12–15 °C, depending on the type of amino-POSS. A significant increase of the glass transition temperature, Tg (DSC data), and the temperature of α relaxation, Tα (DMTA data), by 45–55 °C of the CER matrix with loading of nanofillers was evidenced. CER/POSS films exhibited a higher storage modulus than that of neat CER in the temperature range investigated. It was evidenced that CER/aminopropylisobutyl (APIB)-POSS, CER/N-phenylaminopropyl (NPAP)-POSS, and CER/aminoethyl aminopropylisobutyl (AEAPIB)-POSS nanocomposites induced a more homogenous α relaxation phenomenon with higher Tα values and an enhanced nanocomposite elastic behavior. The value of the storage modulus, E′, at 25 °C increased from 2.72 GPa for the pure CER matrix to 2.99–3.24 GPa for the nanocomposites with amino-functionalized POSS nanoparticles. Furthermore, CER/amino-POSS nanocomposites possessed a higher specific surface area, gas permeability (CO2, He), and diffusion coefficients (CO2) values than those for neat CER, due to an increasing free volume of the nanocomposites studied that is very important for their gas transport properties. Permeability grew by about 2 (He) and 3.5–4 times (CO2), respectively, and the diffusion coefficient of CO2 increased approximately twice for CER/amino-POSS nanocomposites in comparison with the neat CER network. The efficiency of amino-functionalized POSS in improving the thermal and transport properties of the CER/amino-POSS nanocomposites increased in a raw of reactive POSS containing one primary (APIB-POSS) < eight secondary (NPAP-POSS) < one secondary and one primary (AEAPIB-POSS) amino groups. APIB-POSS had the least strongly pronounced effect, since it could form covalent bonds with the CER network only by a reaction of one -NH2 group, while AEAPIB-POSS displayed the most highly marked effect, since it could easily be incorporated into the CER network via a reaction of –NH2 and –NH– groups with –O–C≡N groups from CER.

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“…In the case of reactive R, 3-D POSS molecules with diameters of 1-2 nm, they may graft chemically to polymer structures. New hybrid organic-inorganic CER-based thermosets with hydroxyl- [49,51,52,55,69,72], amino- [50,53], epoxy- [59][60][61][62][63][64][65][66][68][69][70], cyanate- [67], benzoxazinyl- [71] or methacrylate-functionalized [73] POSS units have thus been obtained with improved thermal and mechanical properties.…”

Section: Introductionmentioning

confidence: 99%

Effect of Amino-Functionalized POSS on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites

Grigoryeva,

Fainleib,

Starostenko

et al. 2023

Preprint

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Nanocomposites of cyanate ester resin (CER) filled with three different reactive amino-functionalized polyhedral oligomeric silsesquioxane (POSS) were synthesized and characterized. The addition of a small quantity (0.1 wt.%) of amino-POSS chemically grafted to the CER network led to increasing thermal stability of CER matrix. A significant increase of the glass transition temperature, Tg (DSC data), and the temperature of α relaxation, Tα (DMTA data), by 45-55 оС of CER matrix with loading of nanofillers was evidenced. CER/POSS films exhibited a higher storage modulus than that of neat CER in the temperature range investigated. It was evidenced that CER/aminopropylisobutyl (APIB)-POSS, CER/N-phenylaminopropyl (NPAP)-POSS, and CER/aminoethyl aminopropylisobutyl (AEAPIB)-POSS nanocomposites induced a more homogenous α relaxation phenomenon with higher Tα values and an enhanced nanocomposite elastic behavior. Furthermore, CER/amino-POSS nanocomposites possessed higher specific surface area, gas permeability (CO2, He), and diffusion coefficients (CO2) values than those for neat CER, due to increasing free volume of the nanocomposites studied that is very important for their gas transport properties. Permeability grew respectively by about 2 (He) and 3.5-4 times (СО2), and diffusion coefficient of CO2 increased approximately twice for CER/amino-POSS nanocomposites in comparison with the neat CER network. The efficiency of amino-functionalized POSS in improving the thermal and transport properties of the CER/amino-POSS nanocomposites increased in a raw of reactive POSS containing one primary (APIB-POSS) &lt; eight secondary (NPAP-POSS) &lt; one secondary and one primary (AEAPIB-POSS) amino groups. APIB-POSS had the least strongly pronounced effect, since it could form covalent bonds with the CER network only by reaction of one –NH2 group, while AEAPIB-POSS displayed the most highly marked effect, since it could easily be incorporated into the CER network via reaction of –NH2 and –NH– groups with –O–C≡N groups from CER.

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Toughening of POSS–MPS composites with low dielectric constant prepared with structure controllable micro/mesoporous nanoparticles

Abstract: A promising method to improve the performance of CE composites via combining advantages of POSS and MPS.

Cited by 12 publications

References 29 publications

An ultralow-k dielectric derived from a fluorinated polybenzoxazole composite film with yolk–multishell mesoporous silica nanostructures

An ultralow-k dielectric derived from a fluorinated polybenzoxazole composite film with yolk–multishell mesoporous silica nanostructures

Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites

Effect of Amino-Functionalized POSS on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites

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