“…In bulb-to-bulb distillation of 0.56 g of the crude oil at 50 °C (0.02 mm). 0.45 g was collected containing 55% of 8 according to VPC; the total yield was 57%: IR 1715 (C=0; COO), 1635 cm'1 (C=C); NMR (CDCla) 6.03 (t, 1 H, J = 1.5 Hz, vinylic), 4.18 (q, 2 H, J = 7 Hz, -OCH2CH3), 2.89, 2.31 (AB, 2 H, J = 17 Hz, COCH2), 1.25 (t, 3 H, J = 7 Hz, CH3CH2-); MS M+ 194, 2-(2-Methylallyl)-2,5-dimethylcyclopentanone (31). To 4.37 g (0.039 mol) of potassium tert-butoxide in 80 mL of dry benzene in a 250 mL three-neck flask equipped with a mechanical stirrer, an addition funnel, and a condenser was added 3.56 g (0.31 mol, 4 mL) of 2,5-dimethylcyclopentanone in 10 mL of dry benzene during 10 min.…”