Total Synthesis of Nona-decasaccharide Motif from <i>Ganoderma sinense</i> Polysaccharide Enabled by Modular and One-Pot Stereoselective Glycosylation Strategy

Chen, Zhiyuan; Xiao, Guozhi

doi:10.1021/jacs.4c05188

J. Am. Chem. Soc.

2024

DOI: 10.1021/jacs.4c05188

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Total Synthesis of Nona-decasaccharide Motif from Ganoderma sinense Polysaccharide Enabled by Modular and One-Pot Stereoselective Glycosylation Strategy

Zhiyuan Chen,

Guozhi Xiao

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2024

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One-Pot Assembly of Octasaccharide Motif from Cranberry Arabinoxyloglucan Oligosaccharides

Xiao,

Wan

2024

Synlett

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Chemical synthesis of octasaccharide motif from Cranberry arabinoxyloglucan oligosaccharides with anti-adhesion activities has been achieved for the first time. Synthetic approach highlights the following features: 1) stereoselective constructions of 1,2-cis-Xyl bonds via the combination of reagent modulation and remote participation; 2) modular [1+3+1+3] orthogonal one-pot assembly of the target octasaccharide on the basis of glycosyl ortho-(1-phenylvinyl)benzoate, which avoids the issues such as aglycone transfer associated with one-pot glycosylation based on thioglycosides.

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One-Pot Assembly of Octasaccharide Motif from Cranberry Arabinoxyloglucan Oligosaccharides

Xiao,

Wan

2024

Synlett

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show abstract

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Total Synthesis of Nona-decasaccharide Motif from Ganoderma sinense Polysaccharide Enabled by Modular and One-Pot Stereoselective Glycosylation Strategy

Cited by 1 publication

References 63 publications

One-Pot Assembly of Octasaccharide Motif from Cranberry Arabinoxyloglucan Oligosaccharides

One-Pot Assembly of Octasaccharide Motif from Cranberry Arabinoxyloglucan Oligosaccharides

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