Topological Investigations of Excess Heat Capacities of Binary and Ternary Liquid Mixtures Containing o-Chlorotoluene, Amides and Cyclohexane at 298.15, 303.15 and 308.15 K

Sharma, V.K.; Dua, Rajni; Sharma, Dimple

doi:10.1007/s10953-015-0358-5

Cited by 3 publications

(5 citation statements)

References 75 publications

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“…Data accepted for SimCor method ( Section 2.6 ) are denoted by filled symbols: magenta , this work; red , Sköld et al [ 14 ]; green , Smirnova et al [ 8 ]. Other da-tasets: black , de Visser and Somsen [ 56 ]; black , Bonner and Cerutti [ 57 ]; black , de Visser et al [ 58 ]; black , Kolker et al [ 59 , 62 ]; magenta , Sharma and Dua [ 60 , 61 ]; blue , Prasad et al [ 63 ]; magenta , Checoni and Volpe [ 64 ]; red , Shokouhi et al [ 65 ]; red , Tyczyńska et al [ 66 , 67 ]; blue , Tyczyńska et al [ 68 ]. …”

Section: Resultsmentioning

confidence: 99%

“…(iii) Liquid heat capacities ( Section 2.4 ). For NMF, only two datasets [ 59 , 61 ] reported liquid heat capacities as a function of temperature over a relatively narrow temperature range (see Table 4 ). New measurements in this work extended the available temperature range toward the temperature of melting and even below it.…”

Section: Resultsmentioning

confidence: 99%

“…They were in very good agreement with a single value obtained by drop calorimetry [ 14 ] (see Figure 3 ). Datasets [ 59 , 61 ] differed slightly (though still within combined uncertainties) and were not included in the final correlation. In the case of DMF, reliable adiabatic heat capacities were published by Smirnova et al [ 8 ].…”

Section: Resultsmentioning

confidence: 99%

“…[14]; green , Smirnova et al [8]. Other datasets: black , de Visser and Somsen [56] ; black , Bonner and Cerutti [57] ; black , de Visser et al [58]; black , Kolker et al [59,62]; magenta , Sharma and Dua [60,61]; blue , Prasad et al [63]; magenta , Checoni and Volpe [64]; red , Shokouhi et al [65]; red , Tyczyńska et al [66,67]; blue , Tyczyńska et al [68]. [13]; green , Shealy and Sandler [39]; cya , Blanco et al [43]; dark green , Wang et al [44]; red , Muñoz et al [45].…”

Section: Liquid Heat Capacitiesmentioning

confidence: 99%

“…Sharma and Dua [60,61]; blueMolecules 2024, 29, x FOR PEER REVIEW 9 of 22 Sarge et al [69]. g Due to sufficient amount of sources reporting liquid heat capacity of N,N-Dimethylformamide as a function of temperature, some sources containing heat capacity at single temperature are not listed.…”

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confidence: 99%

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Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide

Růžička,

Štejfa,

Červinka

et al. 2024

Molecules

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An extensive thermodynamic study of N-methylformamide (CAS RN: 123-39-7) and N,N-dimethylformamide (CAS RN: 68-12-2), is presented in this work. The liquid heat capacities of N-methylformamide were measured by Tian–Calvet calorimetry in the temperature interval (250–300) K. The vapor pressures for N-methylformamide and N,N-dimethylformamide were measured using static method in the temperature range 238 K to 308 K. The ideal-gas thermodynamic properties were calculated using a combination of the density functional theory (DFT) and statistical thermodynamics. A consistent thermodynamic description was developed using the method of simultaneous correlation, where the experimental and selected literature data for vapor pressures, vaporization enthalpies, and liquid phase heat capacities and the calculated ideal-gas heat capacities were treated together to ensure overall thermodynamic consistency of the results. The resulting vapor pressure equation is valid from the triple point to the normal boiling point temperature.

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