Abstract:The isothermal and nonisothermal conversions of hydrated and anhydrous forms of cyelotriphosphates of sodium, lithium and ammonium were investigated in different gaseous atmospheres and in vacuum. It was shown that gaseous ammonia in its mixtures with water vapour can accelerate the solid-state splitting of the anionic cycle. A mechanism is suggested for the decycling effect of gaseous ammonia and its mixtures with water vapour.Despite the large number of publications on the transformation of condensed phospha… Show more
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