We consider photon radiation intt events at the upgraded Fermilab Tevatron and the CERN Large Hadron Collider (LHC) as a tool to measure the electric charge of the top quark. We analyze the contributions ofttγ production and radiative top quark decays to p p (−) → γℓ ± νbbjj, assuming that both b-quarks are tagged. With 20 fb −1 at the Tevatron, the possibility that the "top quark" discovered in Run I is actually an exotic charge −4/3 quark can be ruled out at the ≈ 95% confidence level. At the LHC, it will be possible to determine the charge of the top quark with an accuracy of about 10%. *