Intelligent polymeric
materials are of increasing interest in contemporary
technologies due to their low cost, light weight, facile processability,
and inherent ability to change properties, shape, and/or size upon
exposure to an external stimulus. In this study, we consider thermally
programmable shape-memory polymers (SMPs), which typically rely on
chemistry-specific macromolecules composed of two functional species.
An elastic, network-forming component permits stretched polymer chains
to return to their relaxed state, and a switching component affords
at least one thermal transition to regulate fixation of a desired
strain state and return to a previous strain state. Here, we produce
designer shape-memory materials by combining thermoplastic elastomeric
triblock copolymers with a midblock-selective phase-change additive,
thereby yielding shape-memory polymer blends (SMPBs). These materials
not only exhibit tunable switch points but also controllable recovery
kinetics. We further highlight the versatility of SMPBs through laminate
welding for intermediate multishape fabrication and liquid metal inclusion
for shape-memory electronics.