Certain real parameters of a Hamiltonian, when continued to complex values, can give rise to singular points called exceptional points (EP 's), where two or more eigenvalues coincide and the complexified Hamiltonian becomes non-diagonalizable. We show that for a generic d-dimensional topological superconductor/superfluid with a chiral symmetry, one can find EP 's associated with the chiral zero energy Majorana fermions bound to a topological defect/edge. Exploiting the chiral symmetry, we propose a formula for counting the number (n) of such chiral zero modes. We also establish the connection of these solutions to the Majorana fermion wavefunctions in the position space. The imaginary parts of these momenta are related to the exponential decay of the wavefunctions localized at the defect/edge, and hence their change of sign at a topological phase transition point signals the appearance or disappearance of a chiral Majorana zero mode. Our analysis thus explains why topological invariants like the winding number, defined for the corresponding Hamiltonian in the momentum space for a defectless system with periodic boundary conditions, captures the number of admissible Majorana fermion solutions for the position space Hamiltonian with defect(s). Finally, we conclude that EP 's cannot be associated with the Majorana fermion wavefunctions for systems with no chiral symmetry, though one can use our formula for counting n, using complex k solutions where the determinant of the corresponding BdG Hamiltonian vanishes. Introduction -The Hamiltonian operator can contain certain real parameters, which on being continued to complex values, give rise to singular points where the operator becomes non-diagonalizable. These are called exceptional points (EP 's), at which two or more of the eigenvalues coalesce and the norm of at least one eigenvector of the complexified Hamiltonian vanishes [1][2][3][4][5][6][7]. The concept of EP 's is similar to that of a degeneracy point, but with the important difference that all the energy eigenvectors cannot be made mutually orthogonal. In previous works, EP 's have been used [8][9][10][11][12] to describe topological phases of matter associated with zero energy Majorana bound states (MBSs) in one-dimensional (1d) topological superconductors/superfluids.The first-quantized Hamitonians describing fully gapped noninteracting topological insulators and superconductors in d-dimensions can be classified into ten symmetry classes [13,14] in terms of nonspatial symmetries, i.e., symmetries that act locally in the position space, namely time-reversal symmetry (TRS), particlehole symmetry (PHS), and chiral symmetry. Recently, it has been realized [15][16][17][18][19][20][21] that the complete classification should include topological states protected by crystalline symmetries (such as mirror reflections and rotations), which are spatial symmetries acting nonlocally in the position space.A superconductor is described by a Bogoliubov de Gennes (BdG) Hamiltonian (H BdG ), which has an exact PHS, in add...