Chalcogenide
phase-change materials (PCMs) exhibit low absorption
losses in the mid-infrared (MIR) region, which can be exploited for
MIR photonic applications. Furthermore, they show a significant change
in the optical properties with phase transformation. Surface-enhanced
infrared absorption spectroscopy using metamaterials has shown great
potential for detecting molecular fingerprint vibrations in the MIR
region. However, these metamaterials have a very narrow bandwidth,
limiting the range of molecular fingerprint detection. In this work,
we numerically demonstrate a PCM-based metamaterial absorber for molecular
fingerprint retrieval in the MIR region. By modulating the phase of
the PCM, i.e., Ge2Sb2Te5, the resonant
absorption of the metamaterial can be tuned to a broad range. Temporal
coupled-mode theory is employed to determine the optimal design of
the tunable metamaterial for enhanced sensitivity. By manipulating
the phase of the PCM and employing two metapixels, we demonstrate
a wide detection range spanning from 940 to 1860 cm–1. We use this technique to detect distinct vibrational fingerprints
of different analytes, such as poly(methyl methacrylate) and protein.
Furthermore, we show that by integrating the sensing platform with
a microheater, the resonant absorption can be dynamically reconfigured
by applying voltage pulses. Our results indicate that the proposed
tunable sensor holds promise for detecting multiple molecular signatures
and chemical identification. We believe that this work paves the way
toward an effective and miniaturized design of optical sensors in
the MIR region.