Abstract:In the present work, we
study the transient laser-induced formation of 4-nitrophenolate (4-NPO<sup>-</sup>)
in the ground electronic state and subsequent proton transfer reaction with
acetic acid and water with numerical calculations and laser flash photolysis. We
employ the Debye-Smoluchowski spherically-symmetric diffusion model of photoacid
proton transfer to determine experimental conditions for studying thermally
activated chemical reactions in the ground electronic state. Numerically calculat… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.