Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.

Abstract

Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10-10 11 molecule cm-3 for OH at 2870nm, 10 11 molecule cm-3 for HO 2 at 1509nm, and 10 11 molecule cm-3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.