ABSTRACT. Snow and firn samples from 2 and 5 m deep pits were analyzed for seven sites on the Ross Ice Shelf, Antarctica. Na, Mg, Ca, and K concentrations change with depth, the range of concentrations being approximately 10 : I for all four elements. The changes in concentrations for the four elements at any one site are highly correlated, suggesting that the impurities are introduced into the snow-pack simultaneously by the same mechanisms.Pronounced periodic stru cture of the vertical chemical profiles leads to strong correlations (y> o.g) of the chemical features from site to site separated by distances up to 440 km.Assuming that the observed chemical features are periodic as a function of depth due to temporal variations caused by large-scale phenomena, then the wavelength (in depth) of these features should be proportional to the accumulation. Under the assumptions, the linear regression ratio of one site to another will give the relative accumulations at these sites. The ratios of snow accumulation estimated by these chemical methods agree, within a few per cent, with the ratios for the same sites estimated by total ,B-activity or stratigraphic methods.It is suggested that the chemical variations with depth are caused by meteorological events which may have seasonal changes in frequency and intensity. It is also suggested that the most-favored season for the production of chemical-concentration maxima is autumn because of the documented higher frequency of precipitating storms on the Ross Ice Shelf and the minimum in sea-ice extent at that time of year.
RESUME. L' estimation des taux d' accumulation de la neige en Antarctique par des methodes chimiques.On a analyse des echan tillons de neige et glace issus de carottages a 2 et 5 m de profondeur en sept si tes du Ross Ice Shelf en Antarctique. Les concentrations en Na, Mg, Ca et K varient avec la profondeur, le rapport des concentrations extremes etant approximativement de 10 pour I pour to us ces elements. Les variations des concentrations pour les quatre elements en un site sont etroitement correlees, ce qui suggere que les impuretes proviennent des memes causes.De fortes correlations temporelles (avec des coefficients de correlation superieurs a o,g) existent entre les variations chimiques d'un site a un autre separe par des distances allant jusqu'a 440 km.Comme les rapports des profondeurs des particularites chimiques en differents sites sont semblables aux rapports entre les accumulations de neige a ces memes sites, on peut utiliser les variations chimiques pour estimer les accumulations relatives. Les taux d'accumulation de la neige estimes par ces resultats chimiques concordent a quelques pour cent pres, avec les taux d'accumulation dans les memes sites estimes grace a la radiation f3 totale ou par des methodes stratigraphiques.On emet I'hypothese que les variations chimiques avec la profondeur ont pour origine des evenements meteorologiques qui peuvent avoir des variations saisonnieres en frequence et en intensite. La saison la plus favorable pour ...