“…Laser multiphoton ionization is useful in detecting a weak ionization signil because it has an advantage in sensitivity due to the use of a strong light source and tightly focused light enables the signal to increase even at low laser power [9][10][11]. Mechanism of the resonance enhanced multiphoton ionization (REMPI) can be probed by the two-color ionization method where one laser is used for the excitation to the intermediate state and the second laser for ionization [1,2,11]. Hoffman and Albrecht have measured weak ionization signal of N,N,N',N',-tetramethylphenylenediamine near the threshold by means of the two-color method [3].…”