Abstract:Hydrogen bonded liquids like water present a rich thermodynamic behaviour due to the strength and directionality of the bonds. In a recent paper a geometric model based on Bernal's model for liquids was proposed to study the effects of the hydrogen bonds on the phase transitions of water, under pressure and temperature variations. Water molecules were assumed to stay at the vertices of coordination r (r = 4, 5, 6) of perfectly tiled polygons, and to have four links which allow up to four hydrogen bonds per par… Show more
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