This paper describes the influence of cathode configuration on performance of an arcjet thruster using dimethyl ether (DME) propellant. DME, an ether compound, has suitable characteristics for a space propulsion system; DME is storable in a liquid state without being kept under a high pressure, and requires no sophisticated temperature management such as a cryogenic device. DME can be gasified and liquefied simply by adjusting temperature whereas hydrazine, a conventional propellant, requires an iridium-based particulate catalyst for its gasification. In this study, thrust of a 1-kW class DME arcjet thruster is measured at a discharge current of 13 A, DME mass flow rates ranging 15 to 60 mg/s under three cathode configurations: flat-tip rods of 2 and 4 mm in diam. and 4-mm-diam. rod having a cavity of 2 mm in diameter. Thrust measurements show that thrust is increased with propellant mass flow rate. Among the tested cathodes, the flat-tip rod of 4 mm in diam. with 55 mg/s DME flow rate yielded the highest performance: specific impulse of 330 s, thrust of 0.18 N, discharge power of 1400 W and specific power of 25 MJ/kg.