A high power laser (ω 0 , k 0 ), propagating through a two-ion-species plasma, produces oscillatory electron velocity at the second harmonic due to V × B force. This velocity parametrically couples an ion acoustic wave (ω, k) and a scattered electromagnetic wave (ω 1 , k 1 ), where ω 1 = ω − 2ω 0 , k 1 = k − 2k 0 causing second harmonic Brillouin scattering. The growth rate, far above the threshold, scales linearly with laser intensity. It has maximum growth rate slightly tilted to side scattering and vanishes for back scattering. The presence of light ion species introduces linear damping on the ion mode, diminishing the growth rate of the parametric instability.